TRIMETHYL(PHENYL)TIN

Names

[ CAS No. ]:
934-56-5

[ Name ]:
TRIMETHYL(PHENYL)TIN

[Synonym ]:
Trimethylphenylstannane
MFCD00134316
phenyltrimethylstannane
PHENYLTRIMETHYLTIN
2-trimethylstannylbenzene
Stannane,trimethylphenyl

Chemical & Physical Properties

[ Density]:
1.327g/mLat 25°C(lit.)

[ Boiling Point ]:
88ºC16 mm Hg(lit.)

[ Melting Point ]:
-51ºC(lit.)

[ Molecular Formula ]:
C9H14Sn

[ Molecular Weight ]:
240.90800

[ Flash Point ]:
76.1ºC

[ Exact Mass ]:
242.01200

[ LogP ]:
2.23180

[ Index of Refraction ]:
n20/D 1.5357(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300-H310-H330-H410

[ Precautionary Statements ]:
P260-P264-P273-P280-P284-P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T+: Very toxic;N: Dangerous for the environment;

[ Risk Phrases ]:
26/27/28-50/53

[ Safety Phrases ]:
26-27-28-45-60-61

[ RIDADR ]:
UN 2788 6.1/PG 3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • trimethyltin bromide
  • Trichloro(phenyl)stannane
  • phenyl(trimethylstannyl)methanone
  • Trimethyltin chloride
  • sodium
  • N,N,N-Trimethylanilinium iodide
  • Phosphoric acid,diethyl phenyl ester
  • Bromobenzene
  • sodium,trimethyltin
  • phenylmagnesium bromide

DownStream

  • 4-chloro-2-phenyl-quinoline
  • 2-Fluorobenzophenone
  • 4-Biphenylylmethanol
  • 4-Biphenylcarboxylic acid
  • Benzophenone
  • 4-Nitrobenzophenone
  • nitrobenzene
  • 2-Phenylacetophenone
  • Benzamide,N-(diphenylmethyl)-
  • Benzenemethanol, a-pentyl-

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Beyond fullerenes: design of nonfullerene acceptors for efficient organic photovoltaics.

J. Am. Chem. Soc. 136(41) , 14589-97, (2014)

New electron-acceptor materials are long sought to overcome the small photovoltage, high-cost, poor photochemical stability, and other limitations of fullerene-based organic photovoltaics. However, al...


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