6-Methylpicolinic acid

Names

[ CAS No. ]:
934-60-1

[ Name ]:
6-Methylpicolinic acid

[Synonym ]:
6-Methylpicolinic acid
6-methylpyridine-2-carboxylic acid
MFCD00023481
6-Methyl-2-pyridinecarboxylic acid
EINECS 213-287-4
2-Pyridinecarboxylic acid, 6-methyl-
picolinic acid, 6-methyl-

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
283.6±20.0 °C at 760 mmHg

[ Melting Point ]:
130 °C

[ Molecular Formula ]:
C₇H₇NO₂

[ Molecular Weight ]:
137.14

[ Flash Point ]:
125.3±21.8 °C

[ Exact Mass ]:
137.047684

[ PSA ]:
50.19000

[ LogP ]:
0.36

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.561

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39-S36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

6-Methyl-2-pyridinemethanol
2-(Bromomethyl)-6-methylpyridine
2-Bromo-6-methylpyridine
2,6-lutidine
Methyl 6-methylpyridine-2-carboxylate
6-Methyl-2-pyridinecarboxaldehyde
3-Methylcatechol
2-(6-Methyl-2-pyridinyl)ethanol
2,6-Lutidine oxide
(6-Methylpyridin-2-yl)methyl acetate

DownStream

ETHYL 6-METHYL-2-PYRIDINECARBOXYLATE 9&
2-(6-methylpyridin-2-yl)-1,3-benzothiazole
Methyl 6-(bromomethyl)picolinate
Methyl 6-methylpyridine-2-carboxylate
1-methyl-5-[[1-methyl-2-(6-methylpyridin-2-yl)benzimidazol-5-yl]methyl]-2-(6-methylpyridin-2-yl)benzimidazole
2-Pyridinecarbonyl chloride, 6-methyl- (9CI)
1-ethyl-5-[[1-ethyl-2-(6-methylpyridin-2-yl)benzimidazol-5-yl]methyl]-2-(6-methylpyridin-2-yl)benzimidazole
Methyl 6-(chloromethyl)-2-pyridinecarboxylate
2-Pyridinecarboxylicacid, 6-methyl-, 1-oxide
6-methylpyridine-2-carbonyl chloride,hydrochloride

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Synthesis of benzoxazolylpyridine nickel complexes and their efficient dimerization of ethylene to alpha-butene.

Dalton Trans. (41) , 5645-51, (2008)

A series of new nickel complexes bearing benzoxazolylpyridines was synthesized and characterized by FT-IR spectroscopic and elemental analysis. The molecular structures of two representative complexes...

Chloro(mu-6-methylpyridine-2-carboxylato)bis(6-methylpyridine-2-carboxylato)triphenylchromium(III)tin(IV) chlorotriphenyltin(IV).

Acta Crystallogr. C 62(Pt 12) , m581-3, (2006)

The title compound, [CrSn(C6H5)3(C7H6NO2)3Cl][Sn(C6H5)3Cl(CH4O)], was obtained from the reaction of Ph3SnCl with the complex [Cr(C7H6NO2)3] in methanol. The structure contains [Ph3SnCl(MeOH)] (A) and ...

Catalytic dehydrogenation of cyclooctane with neutral iridium (I) complexes. Taubmann S and Alt HG.

J. Organomet. Chem. 693(10) , 1808-14, (2008)