2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide

Names

[ CAS No. ]:
934506-10-2

[ Name ]:
2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide

[Synonym ]:
tBuXPhosAuNTf
XPhos AuNTf2

Chemical & Physical Properties

[ Molecular Formula ]:
C₃₅H₄₉AuF₆NO₄PS₂

[ Molecular Weight ]:
953.82900

[ Exact Mass ]:
953.24100

[ PSA ]:
98.63000

[ LogP ]:
13.71480

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Articles

Gold(I)-catalyzed isomerization of allenyl carbinol esters: an efficient access to functionalized 1,3-butadien-2-ol esters.

Org. Lett. 9 , 985, (2007)

A study concerning the gold(I)-catalyzed rearrangement of diversely substituted allenyl carbinol esters into functionalized 1,3-butadien-2-ol esters is described. The mild conditions employed allow th...

Gold(I)-catalyzed 5-endo hydroxy- and alkoxycyclization of 1,5-enynes: efficient access to functionalized cyclopentenes.

Angew. Chem. Int. Ed. Engl. 46 , 1141, (2007)

An unusual access to medium sized cycloalkynes by a new gold(I)-catalysed cycloisomerisation of diynes.

Chemistry 15 , 8966, (2009)

5-[(tert-butoxy)carbonyl]-1H,4H,5H,6H,7H,8H-pyrrolo[3,2-c]azepine-2-carboxylic acid
2-(8-Bromo-1-oxo-1,2-dihydrophthalazin-2-yl)acetic acid
tert-butyl N-methyl-N-{[(1r,4r)-4-(bromomethyl)cyclohexyl]methyl}carbamate
Tert-butyl 7-(aminomethyl)-6,9-dioxa-2-azaspiro[4.5]decane-2-carboxylate
Methyl 3-iodoquinoline-7-carboxylate
7,7-Difluorospiro[3.5]nonane-2-carbaldehyde
N-{[1-(5,6-dimethylpyrimidin-4-yl)piperidin-4-yl]methyl}-5-fluoro-N,6-dimethylpyrimidin-4-amine
1-Tert-butyl-3-cyclopropyl-4-iodo-pyrazole
4-(5-Bromo-4-methoxypyrimidin-2-yl)-2-(morpholine-4-carbonyl)morpholine
2-(4-{[(9H-fluoren-9-yl)methoxy]carbonyl}-6-(hydroxymethyl)morpholin-2-yl)acetic acid

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