P-TOLYL CHLOROFORMATE

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Names

[ CAS No. ]:
937-62-2

[ Name ]:
P-TOLYL CHLOROFORMATE

[Synonym ]:
4-tolyl chloroformate
EINECS 213-332-8
p-Tolyl chloroforMate 5GR
1-chlorocarbonyloxy-4-methyl-benzene
Chloroformic acid p-tolyl ester
4-toluyl chloroformate
Chloroformic acid 4-methylphenyl ester
Phenyl chloroformate
4-Methylphenyl chloroformate
MFCD00013255

Chemical & Physical Properties

[ Density]:
1.234g/cm3

[ Boiling Point ]:
207.2ºC at 760mmHg

[ Molecular Formula ]:
C8H7ClO2

[ Molecular Weight ]:
170.59300

[ Flash Point ]:
85.6ºC

[ Exact Mass ]:
170.01300

[ PSA ]:
26.30000

[ LogP ]:
2.73260

[ Appearance of Characters ]:
Liquid | Clear colorless

[ Index of Refraction ]:
n20/D 1.5099(lit.)

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H314-H331

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
26-27-36/37/39-45

[ RIDADR ]:
UN 3277 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • p-Cresol
  • Triphosgene
  • phosgene
  • N,N-Dimethylaniline

DownStream

  • tert-butyl (4-methylphenyl) carbonate
  • 4-Hydroxybenzyl chloride
  • Carbonic acid methyl 4-methylphenyl ester
  • (4-methylphenyl) carbamate
  • 4-(Methoxymethyl)phenol
  • 3-[(4-hydroxyphenyl)methyl]pentane-2,4-dione
  • 4-(diethoxyphosphorylmethyl)phenol
  • Carbonic acid,(4-methoxyphenyl)methyl 4-methylphenyl ester
  • (3,4-dimethoxyphenyl)methyl (4-methylphenyl) carbonate
  • 4-Hydroxyphenylacetonitrile

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Reaction of aryl chloroformates with dimethylformamide. Facile in situ synthesis of. alpha.-chlorocresols. Pattison VA, et al.

J. Org. Chem. 33(3) , 1084-87, (1968)


More Articles

Related Compounds

  • P-Tolyl Chloroformate
  • P-TOLYL-M-TOLYLAMINOACETICACID
  • p-tolyl triphenylmethyl sulphone
  • p-Tolyl[o-(phenylthio)phenyl]methanol
  • p-Tolyl-4-aminosalicylate
  • P-TOLYL TRIFLATE
  • 7-[5-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpentanoyl]-7-azabicyclo[2.2.1]heptane-2-carboxylic acid
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • (3R)-3-hydroxy-3-(3-methoxy-2-nitrophenyl)propanoic acid
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 4-Bromo-6-chloro-1-methoxy-2,7-naphthyridine
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • {1-[3-(1H-1,2,3,4-tetrazol-5-yl)phenyl]cyclopropyl}methanol