P-TOLYL CHLOROFORMATE

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Names

[ CAS No. ]:
937-62-2

[ Name ]:
P-TOLYL CHLOROFORMATE

[Synonym ]:
4-tolyl chloroformate
EINECS 213-332-8
p-Tolyl chloroforMate 5GR
1-chlorocarbonyloxy-4-methyl-benzene
Chloroformic acid p-tolyl ester
4-toluyl chloroformate
Chloroformic acid 4-methylphenyl ester
Phenyl chloroformate
4-Methylphenyl chloroformate
MFCD00013255

Chemical & Physical Properties

[ Density]:
1.234g/cm3

[ Boiling Point ]:
207.2ºC at 760mmHg

[ Molecular Formula ]:
C8H7ClO2

[ Molecular Weight ]:
170.59300

[ Flash Point ]:
85.6ºC

[ Exact Mass ]:
170.01300

[ PSA ]:
26.30000

[ LogP ]:
2.73260

[ Appearance of Characters ]:
Liquid | Clear colorless

[ Index of Refraction ]:
n20/D 1.5099(lit.)

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H314-H331

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
26-27-36/37/39-45

[ RIDADR ]:
UN 3277 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • p-Cresol
  • Triphosgene
  • phosgene
  • N,N-Dimethylaniline

DownStream

  • tert-butyl (4-methylphenyl) carbonate
  • 4-Hydroxybenzyl chloride
  • Carbonic acid methyl 4-methylphenyl ester
  • (4-methylphenyl) carbamate
  • 4-(Methoxymethyl)phenol
  • 3-[(4-hydroxyphenyl)methyl]pentane-2,4-dione
  • 4-(diethoxyphosphorylmethyl)phenol
  • Carbonic acid,(4-methoxyphenyl)methyl 4-methylphenyl ester
  • (3,4-dimethoxyphenyl)methyl (4-methylphenyl) carbonate
  • 4-Hydroxyphenylacetonitrile

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Reaction of aryl chloroformates with dimethylformamide. Facile in situ synthesis of. alpha.-chlorocresols. Pattison VA, et al.

J. Org. Chem. 33(3) , 1084-87, (1968)


More Articles

Related Compounds

  • P-Tolyl Chloroformate
  • P-TOLYL-M-TOLYLAMINOACETICACID
  • p-tolyl triphenylmethyl sulphone
  • p-Tolyl[o-(phenylthio)phenyl]methanol
  • p-Tolyl-4-aminosalicylate
  • P-TOLYL TRIFLATE
  • 6,7-Dihydro-I(2)-methyl-I(2)-(2-methylpropyl)thieno[3,2-c]pyridine-5(4H)-ethanamine
  • I(2),2-Dimethyl-I(2)-(3-methylbutyl)-4-morpholineethanamine
  • 3-[(2-Hydroxy-4-methylphenyl)formamido]propanoic acid
  • (R)-4-(1-((tert-Butoxycarbonyl)amino)-2-hydroxyethyl)phenyl trifluoromethanesulfonate
  • 1-(2,5-Difluorobenzoyl)piperidin-4-amine
  • 6-[4-(Pyridin-2-yl)piperazin-1-yl]pyridine-3-carbonitrile
  • 2-(4-Methyl-1-piperazinyl)-4-pyridinecarbothioamide
  • N-(3-amino-4-methylphenyl)cyclopropanecarboxamide
  • 3-(1H-1,3-benzodiazole-5-amido)benzoic acid
  • 2-(Cyclohexyloxy)ethanethioamide
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