Lipoamide

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Names

[ CAS No. ]:
940-69-2

[ Name ]:
Lipoamide

[Synonym ]:
lipoicin
dl-thioctic acid amide
thioami
5-(1,2-Dithiolan-3-yl)pentanamide
EINECS 213-375-2
vitaminn
MFCD00005475
thioctic amide
lipozyme
lypoaran
lipoacin
ticolin
lipoamid
lipamide

Chemical & Physical Properties

[ Density]:
1.169 g/cm3

[ Boiling Point ]:
399.2ºC at 760 mmHg

[ Melting Point ]:
127-129ºC(lit.)

[ Molecular Formula ]:
C8H15NOS2

[ Molecular Weight ]:
205.34100

[ Flash Point ]:
195.2ºC

[ Exact Mass ]:
205.06000

[ PSA ]:
93.69000

[ LogP ]:
2.88610

[ Index of Refraction ]:
1.562

[ Storage condition ]:
2-8°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
JP1185000
CHEMICAL NAME :
1,2-Dithiolane-3-valeramide
CAS REGISTRY NUMBER :
940-69-2
BEILSTEIN REFERENCE NO. :
0122470
LAST UPDATED :
199612
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C8-H15-N-O-S2
MOLECULAR WEIGHT :
205.36
WISWESSER LINE NOTATION :
T5SSTJ C4VZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1980 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NIIRDN Drugs in Japan (Ethical Drugs). (Yakugyo Jiho Co., Ltd., Tokyo, Japan) Volume(issue)/page/year: 6,454,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NIIRDN Drugs in Japan (Ethical Drugs). (Yakugyo Jiho Co., Ltd., Tokyo, Japan) Volume(issue)/page/year: 6,454,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1700 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NIIRDN Drugs in Japan (Ethical Drugs). (Yakugyo Jiho Co., Ltd., Tokyo, Japan) Volume(issue)/page/year: 6,454,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
620 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NIIRDN Drugs in Japan (Ethical Drugs). (Yakugyo Jiho Co., Ltd., Tokyo, Japan) Volume(issue)/page/year: 6,454,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
310 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NIIRDN Drugs in Japan (Ethical Drugs). (Yakugyo Jiho Co., Ltd., Tokyo, Japan) Volume(issue)/page/year: 6,454,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NIIRDN Drugs in Japan (Ethical Drugs). (Yakugyo Jiho Co., Ltd., Tokyo, Japan) Volume(issue)/page/year: 6,454,1982

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
22-24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
JP1185000

[ HS Code ]:
2934999090

Synthetic Route

Precursor & DownStream

Precursor

  • α-Lipoic acid-NHS
  • 6,8-bis-sulfanyloctanamide
  • α-Lipoic Acid

DownStream

  • NAD+
  • 6,8-bis-sulfanyloctanamide
  • Methyl o-methylbenzoate
  • Octanamide

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Sirtuin 4 is a lipoamidase regulating pyruvate dehydrogenase complex activity.

Cell 159(7) , 1615-25, (2014)

Sirtuins (SIRTs) are critical enzymes that govern genome regulation, metabolism, and aging. Despite conserved deacetylase domains, mitochondrial SIRT4 and SIRT5 have little to no deacetylase activity,...

Molecular characterization of the thioredoxin system from Methanosarcina acetivorans.

FEBS J. 281(20) , 4598-611, (2014)

The thioredoxin system, composed of thioredoxin reductase (TrxR) and thioredoxin (Trx), is widely distributed in nature, where it serves key roles in electron transfer and in the defense against oxida...

Catalysis of diaphorase reactions by Mycobacterium tuberculosis lipoamide dehydrogenase occurs at the EH4 level.

Biochemistry 42(7) , 2218-28, (2003)

Lipoamide dehydrogenase catalyzes the reversible NAD(+)-dependent oxidation of the dihydrolipoyl cofactors that are covalently attached to the acyltransferase components of the pyruvate dehydrogenase,...


More Articles


Related Compounds

  • Lipoamide
  • MAL-PEG3-Lipoamide
  • Lipoamide-PEG3-Mal
  • Lipoamide-PEG11-Mal
  • m-dPEG(R)8-Lipoamide
  • m-dPEG12-Lipoamide
  • Tert-butyl 2-(5-formyl-4-hydroxypyridin-3-YL)ethylcarbamate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • (1-(1-(Furan-2-yl)ethyl)piperidin-2-yl)methanol
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine