Fluolead

Suppliers

Names

[ Name ]:
Fluolead

[Synonym ]:
1-tert-butyl-4-trifluorosulfanyl-3,5-dimethylbenzene
Sulfur, [4-(1,1-dimethylethyl)-2,6-dimethylphenyl]trifluoro-
4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride
Fluolead
FSFFR B1 F1 DX1&1&1
1,3-Dimethyl-5-(2-methyl-2-propanyl)-2-(trifluoro-λ-sulfanyl)benzene
4-(tert-Butyl)-2,6-dimethylphenylsulphur trifluoride
MFCD11858620
[4-(tert-Butyl)-2,6-dimethylphenyl]trifluoro-λ4-sulfane
PC5654
4-tert-Butyl-2,6-dimethylphenylsulfurtrifluoride

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
92-93℃ (0.5 Torr)

[ Melting Point ]:
60-61℃ (pentane )

[ Molecular Formula ]:
C₁₂H₁₇F₃S

[ Molecular Weight ]:
250.324

[ Exact Mass ]:
250.100311

[ PSA ]:
25.30000

[ LogP ]:
5.41790

[ Index of Refraction ]:
1.450

[ Storage condition ]:
0-10°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P301 + P310-P305 + P351 + P338-P310

[ Hazard Codes ]:
T

[ Risk Phrases ]:
14-25-34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 3261 8.1/PG 2

[ Packaging Group ]:
II

Articles

Discovery of 4-tert-butyl-2,6-dimethylphenylsulfur trifluoride as a deoxofluorinating agent with high thermal stability as well as unusual resistance to aqueous hydrolysis, and its diverse fluorination capabilities including deoxofluoro-arylsulfinylation with high stereoselectivity.

J. Am. Chem. Soc. 132 , 18199-18205, (2010)

Versatile, safe, shelf-stable, and easy-to-handle fluorinating agents are strongly desired in both academic and industrial arenas, since fluorinated compounds have attracted considerable interest in m...

Kirk, K. L

Org. Process Res. Dev. 2nd ed., 12 , 305-321, (2008)

N-((5-((2-((3-acetamidophenyl)amino)-2-oxoethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)benzamide
N-((5-((2-((5-methyl-1,3,4-thiadiazol-2-yl)amino)-2-oxoethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)benzamide
4-(tert-butyl)-N-((5-((2-oxo-2-(4-phenylpiperazin-1-yl)ethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)benzamide
N-((5-((2-(benzo[d][1,3]dioxol-5-ylamino)-2-oxoethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)-4-(tert-butyl)benzamide
4-(tert-butyl)-N-((5-((2-((2,3-dihydrobenzo[b][1,4]dioxin-6-yl)amino)-2-oxoethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)benzamide
4-(tert-butyl)-N-((5-((2-((4-nitrophenyl)amino)-2-oxoethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)benzamide
N-((5-((2-((4-acetylphenyl)amino)-2-oxoethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)-4-(tert-butyl)benzamide
N-((5-((2-((3-acetamidophenyl)amino)-2-oxoethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)-4-(tert-butyl)benzamide
4-(tert-butyl)-N-((5-((2-(cyclohexylamino)-2-oxoethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)benzamide
4-(tert-butyl)-N-((5-((2-oxo-2-(((tetrahydrofuran-2-yl)methyl)amino)ethyl)thio)-1,3,4-oxadiazol-2-yl)methyl)benzamide

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