4-Chloro-2-Methylaniline
Suppliers
Names
[ CAS No. ]:
95-69-2
[ Name ]:
4-Chloro-2-Methylaniline
[Synonym ]:
4-Chloro-2-methylaniline
fastredtr11
devalredk
Ipsilon
Fast Red TR
4-Chloro-o-toluidine
EINECS 202-441-6
p-chloro-o-methylaniline
BENZENAMINE,4-CHLORO-2-METHYL-
5-chloro-2-amino-toluene
Deval Red TR
1-amino-2-methyl-4-chlorobenzene
N-(4-chloro-2-methylphenyl)picolinamide
2-AMINO-5-CHLOROTOLUENE
MFCD00007842
4-CHLOR-2-METHYLANILIN
2-methyl-4-chloro-aniline
Benzenamine, 4-chloro-2-methyl-
redbasentr
RED TR BASE
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
242.8±20.0 °C at 760 mmHg
[ Melting Point ]:
29 °C
[ Molecular Formula ]:
C7H8ClN
[ Molecular Weight ]:
141.598
[ Flash Point ]:
99.4±0.0 °C
[ Exact Mass ]:
141.034531
[ PSA ]:
26.02000
[ LogP ]:
2.22
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.585
[ Storage condition ]:
2-8°C
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XU5000000
- CHEMICAL NAME :
- o-Toluidine, 4-chloro-
- CAS REGISTRY NUMBER :
- 95-69-2
- BEILSTEIN REFERENCE NO. :
- 0878505
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 22
- MOLECULAR FORMULA :
- C7-H8-Cl-N
- MOLECULAR WEIGHT :
- 141.61
- WISWESSER LINE NOTATION :
- ZR DG B1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1058 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Mammal - cat
- DOSE/DURATION :
- 310 mg/kg
- TOXIC EFFECTS :
- Behavioral - ataxia Gastrointestinal - nausea or vomiting Blood - methemoglobinemia-carboxyhemoglobin
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - wild bird species
- DOSE/DURATION :
- 75 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
MUTATION DATA
- TEST SYSTEM :
- Rodent - mouse
- DOSE/DURATION :
- 200 mg/kg
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 46,305,1977 *** REVIEWS *** IARC Cancer Review:Human Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 48,123,1990 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 30,61,1983 IARC Cancer Review:Group 2A IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 48,123,1990 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-FINLAND;Carcinogen JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-SWITZERLAND:TWA 2 ppm (12 mg/m3);Skin;Carcinogen JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - T0066 No. of Facilities: 77 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 1397 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T0066 No. of Facilities: 16 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 250 (estimated) No. of Female Employees: 250 (estimated)
Safety Information
[ Symbol ]:
GHS06, GHS08, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301-H311-H331-H341-H350-H410
[ Precautionary Statements ]:
P201-P261-P273-P280-P301 + P310-P311
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ Hazard Codes ]:
T:Toxic;N:Dangerousfortheenvironment;
[ Risk Phrases ]:
R23/24/25;R45;R50/53;R68
[ Safety Phrases ]:
S53-S45-S60-S61
[ RIDADR ]:
UN 2239 6.1/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
XU5000000
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1(b)
[ HS Code ]:
2921430090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2921430090
[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%