2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE

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Names

[ Name ]:
2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE

[Synonym ]:
2-TBS-1,3-dithiane
TBS-1,3-dithiane
2-(tert-butyldimethylsilyl)-1,3-dithiane
1-tert-butyldimethylsilyl(1,3)dithiane
2-TBS-1,3-dithinane
MFCD02093667
tert-butyl(1,3-dithian-2-yl)dimethylsilane
t-Butyl[1,3]dithian-2-yldimethylsilane

Chemical & Physical Properties

[ Density]:
1.01 g/mL at 25ºC(lit.)

[ Boiling Point ]:
124ºC5 mm Hg(lit.)

[ Molecular Formula ]:
C₁₀H₂₂S₂Si

[ Molecular Weight ]:
234.49700

[ Flash Point ]:
221 °F

[ Exact Mass ]:
234.09300

[ PSA ]:
50.60000

[ LogP ]:
4.65020

[ Index of Refraction ]:
n20/D 1.531(lit.)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Multicomponent linchpin couplings of silyl dithianes: synthesis of the Schreiber C(16-28) trisacetonide subtarget for mycoticins A and B.

Org. Lett. 1(12) , 2001-4, (1999)

[formula: see text] An efficient synthesis of trisacetonide (+)-11, the Schreiber C(16-28) subtarget for mycoticins A and B, is described. The key synthetic transformation entails a one-flask, five-co...

A general, convergent strategy for the construction of indolizidine alkaloids: total syntheses of (-)-indolizidine 223AB and alkaloid (-)-205B.

J. Org. Chem. 71 , 2547, (2006)

N-Toluenesulfonyl aziridines comprise effective second electrophiles in the solvent controlled three-component linchpin union of silyl dithianes for the stereocontrolled convergent elaboration of prot...

Total synthesis of the neotropical poison-frog alkaloid (-)-205B.

Org. Lett. 7 , 3247, (2005)

[reaction: see text]. A stereocontrolled total synthesis of the neotropical poison-frog alkaloid (-)-205B (1) has been achieved, employing a dithiane three-component linchpin coupling, a one-pot seque...

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N-(4-chlorophenyl)-2-[3-(4-methoxyphenyl)-2-oxo-1,4-diazaspiro[4.6]undec-3-en-1-yl]acetamide
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7h-Pyrrolo[2,3-d]pyrimidine-5-carboxamide,7-(1,1-dimethylethyl)-n-methyl-2-[(4-methylbenzoyl)amino]-
1h-Pyrrolo[2,3-b]pyridine-3-carboxamide,1-(1,1-dimethylethyl)-6-[(4-methylbenzoyl)amino]-n-(1-methylethyl)-
1h-Pyrrolo[2,3-b]pyridine-3-carboxamide,1-(1,1-dimethylethyl)-n-ethyl-6-[(4-methylbenzoyl)amino]-
1h-Pyrrolo[2,3-b]pyridine-3-carboxamide,1-(1,1-dimethylethyl)-6-[(4-methylbenzoyl)amino]-n-(2-methylpropyl)-