2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE

Suppliers

Names

[ Name ]:
2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE

[Synonym ]:
2-TBS-1,3-dithiane
TBS-1,3-dithiane
2-(tert-butyldimethylsilyl)-1,3-dithiane
1-tert-butyldimethylsilyl(1,3)dithiane
2-TBS-1,3-dithinane
MFCD02093667
tert-butyl(1,3-dithian-2-yl)dimethylsilane
t-Butyl[1,3]dithian-2-yldimethylsilane

Chemical & Physical Properties

[ Density]:
1.01 g/mL at 25ºC(lit.)

[ Boiling Point ]:
124ºC5 mm Hg(lit.)

[ Molecular Formula ]:
C₁₀H₂₂S₂Si

[ Molecular Weight ]:
234.49700

[ Flash Point ]:
221 °F

[ Exact Mass ]:
234.09300

[ PSA ]:
50.60000

[ LogP ]:
4.65020

[ Index of Refraction ]:
n20/D 1.531(lit.)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Multicomponent linchpin couplings of silyl dithianes: synthesis of the Schreiber C(16-28) trisacetonide subtarget for mycoticins A and B.

Org. Lett. 1(12) , 2001-4, (1999)

[formula: see text] An efficient synthesis of trisacetonide (+)-11, the Schreiber C(16-28) subtarget for mycoticins A and B, is described. The key synthetic transformation entails a one-flask, five-co...

A general, convergent strategy for the construction of indolizidine alkaloids: total syntheses of (-)-indolizidine 223AB and alkaloid (-)-205B.

J. Org. Chem. 71 , 2547, (2006)

N-Toluenesulfonyl aziridines comprise effective second electrophiles in the solvent controlled three-component linchpin union of silyl dithianes for the stereocontrolled convergent elaboration of prot...

Total synthesis of the neotropical poison-frog alkaloid (-)-205B.

Org. Lett. 7 , 3247, (2005)

[reaction: see text]. A stereocontrolled total synthesis of the neotropical poison-frog alkaloid (-)-205B (1) has been achieved, employing a dithiane three-component linchpin coupling, a one-pot seque...

2-tert-butyldimethylsilyl-1,3-dimethylazulene
2-(tert-Butyldimethylsilyl)-1,3-phenylene Bis(trifluoromethanesulfonate)
2-(tert-butyldimethylsilyl)-1,3-diphenylbutan-1-one
(Z)-2-(tert-butyldimethylsilyl)-1,3-diphenylprop-2-en-1-one
1,4-bis[2-(tert-butyldimethylsilyl)[1,3]-dithian-2-yl]butane
2-tert-Butyl-1,3-dithiane-5,5-dithiol
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
2-Bromo-4-ethynyl-1,3-dimethylbenzene
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine
Methyl 3-(3-amino-2-hydroxypropyl)benzoate