(S)-Garner's Aldehyde

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Names

[ Name ]:
(S)-Garner's Aldehyde

[Synonym ]:
(4S)-2,2-Dimethyl-1,3-oxazolidine-4-carboxaldehyde, N-BOC protected
(S)-4-Formyl-2,2-dimethyl-oxazolidine-3-carboxylic tert-butyl ester
tert-Butyl (4R)-4-formyl-2,2-dimethyl-1,3-oxazolidine-3-carboxylate
Garner's aldehyde
tert-Butyl (4S)-4-formyl-2,2-dimethyl-1,3-oxazolidine-3-carboxylate
(R)-4-Formyl-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester
tert-Butyl-(4S)-4-formyl-2,2-dimethyl-1,3-oxazolidin-3-carboxylat
(4S)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylic acid tert-butyl ester
(-)-Garner's Aldehyde
2-Methyl-2-propanyl (4S)-4-formyl-2,2-dimethyl-1,3-oxazolidine-3-carboxylate
(−)-N-Boc-N,O-isopropylidene-L-serinal
3-Oxazolidinecarboxylic acid, 4-formyl-2,2-dimethyl-, 1,1-dimethylethyl ester, (4R)-
3-Oxazolidinecarboxylic acid, 4-formyl-2,2-dimethyl-, 1,1-dimethylethyl ester, (4S)-
MFCD00674064
2-Methyl-2-propanyl (4R)-4-formyl-2,2-dimethyl-1,3-oxazolidine-3-carboxylate
(R)-Garner aldehyde
Garners aldehyde
(-)-N-Boc-N,O-isopropylidene-L-serinal
(4S)-2,2-Dimethyl-1,3-oxazolidine-4-carboxaldehyde N-BOC protected
TERT-BUTYL (R)-(+)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE
(4S)-4-formyl-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester
(R)-3-Boc-4-formyl-2,2-dimethyl-1,3-oxazolidine

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
302.7±42.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₁H₁₉NO₄

[ Molecular Weight ]:
229.273

[ Flash Point ]:
136.9±27.9 °C

[ Exact Mass ]:
229.131409

[ PSA ]:
55.84000

[ LogP ]:
1.15

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.500

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
37/39-26-36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

3-O-tert-butyl 4-O-methyl (4S)-2,2-dimethyl-1,3-oxazolidine-3,4-dicarboxylate
(R)-N-Boc-2,2-Dimethyl-4-hydroxymethyloxazolindine
(R)-3-BOC-4-(METHOXYMETHYLCARBAMOYL)-2,2-DIMETHYLOXAZOLIDINE
BOC-D-SER-OME
Di-tert-butyl dicarbonate
Boc-Ser-OH
Boc-Ser-OMe
Boc-Ser(Bzl)-ol
N-Boc-O-benzyl-L-serine methyl ester

DownStream

tert-butyl (4R)-4-[(R)-hydroxy-[(2R)-5-oxo-2H-furan-2-yl]methyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate
6,7-N,O-Isopropylidene-6-[(tert-butoxycarbonyl)amino]-2,3,6-trideoxy-D-ribo-hept-2-enono-1,4-lactone
(S)-2-(TOLUENE-4-SULFONYLOXY)-PROPIONICACID
(R)-N-BOC-2,2-DIMETHYL-4-VINYLOXAZOLIDINE
(S)-2-(N-BOC-AMINO)-N-BENZYLOXY-3-HYDROXY-3-METHYLBUTYRAMIDE
Carbamic acid, (1-methylene-2-propynyl)-, 1,1-dimethylethyl ester (9CI)
methyl (2S)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-[(2R,3R,4R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]acetate

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Gamma-fluorinated analogues of glutamic acid and glutamine.

Amino Acids 24 , 245-261, (2003)

Gamma-fluorinated analogues of glutamic acid and glutamine are compounds of biological interest. Syntheses of such compounds are extensively reviewed in this article. 4-fluoroglutamic acid was prepare...