DIETHYLALUMINUM CHLORIDE

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Names

[ CAS No. ]:
96-10-6

[ Name ]:
DIETHYLALUMINUM CHLORIDE

[Synonym ]:
chloro(diethyl)alumane
MFCD00000459
EINECS 202-477-2

Chemical & Physical Properties

[ Density]:
0.887 g/mL at 25 °C

[ Boiling Point ]:
125°C 50mm

[ Melting Point ]:
-85°C

[ Molecular Formula ]:
C4H10AlCl

[ Molecular Weight ]:
120.55700

[ Flash Point ]:
−9 °F

[ Exact Mass ]:
120.02900

[ LogP ]:
2.63730

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BD0558000
CHEMICAL NAME :
Aluminum, chlorodiethyl-
CAS REGISTRY NUMBER :
96-10-6
LAST UPDATED :
199712
DATA ITEMS CITED :
15
MOLECULAR FORMULA :
C4-H10-Al-Cl

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
11 gm/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1215,1986 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6233 No. of Facilities: 14 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 2506 (estimated) No. of Female Employees: 328 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H250-H260-H304-H314-H336-H361f-H373-H411

[ Precautionary Statements ]:
P210-P222-P223-P231 + P232-P370 + P378-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Highlyflammable;C:Corrosive;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R14;R17;R34;R48/20;R51/53;R62;R65

[ Safety Phrases ]:
S36/37/39-S45-S62-S61-S43-S26

[ RIDADR ]:
UN 3394 4.2/PG 1

[ WGK Germany ]:
2

[ RTECS ]:
BD0558000

[ Packaging Group ]:
I

[ Hazard Class ]:
4.3

[ HS Code ]:
2903199000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Triethylaluminum
  • Germanium chloride
  • monochloroethane
  • Zinc chloride
  • Chloroform
  • Titanium tetrachloride
  • ethene
  • Dichloroethylaluminum
  • Aluminum Powder

DownStream

  • Diethyl (1-phenylpropyl)malonate
  • n-ethyl-4-nitroaniline
  • ethane
  • Methyl n-propyl ether
  • Phenyl ethyl ketone
  • 3-Phenyl-3-hydroxy-hexanon-(4)
  • 1-Butanone,2-ethyl-2-hydroxy-1-phenyl-
  • 1-phenylbutane-1,2-dione
  • 2-(1H-TETRAZOL-5-YL)PHENOL
  • TRANS-3-HEXEN-1-OL

Customs

[ HS Code ]: 2903199000

[ Summary ]:
2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Related Compounds

  • Benzoyl chloride, 2-(4-morpholinyl)-5-nitro
  • Cyclohexanesulfenyl chloride
  • Benzoyl chloride, 4-[(acetyloxy)methyl]- (9CI)
  • Benzeneethanesulfenyl chloride, alpha-chloro-beta-oxo- (9CI)
  • Ethanesulfonyl chloride
  • Oxiranecarbonyl chloride, 2-methyl-3-phenyl-, trans- (9CI)
  • 3-(4-(Trifluoromethyl)pyridin-3-yl)thiazolidine
  • 4-(Trifluoromethyl)-3-(3,3,3-trifluoropropoxy)pyridine
  • 3-(1,1,1,3,3,3-Hexafluoropropan-2-yloxy)-4-(trifluoromethyl)pyridine
  • N,N-Dimethyl-1-(4-(trifluoromethyl)pyridin-3-yl)piperidin-4-amine
  • 5-(3,3-Difluoropiperidin-1-yl)-2-(trifluoromethyl)pyridine
  • 5-(4,4-Difluoropiperidin-1-yl)-2-(trifluoromethyl)pyridine
  • 5-(3,3-Difluoroazetidin-1-yl)-2-(trifluoromethyl)pyridine
  • 5-(3,3-Difluoropyrrolidin-1-yl)-2-(trifluoromethyl)pyridine
  • 3-(6-(Trifluoromethyl)pyridin-3-yl)thiazolidine
  • 2-(Trifluoromethyl)-5-(3,3,3-trifluoropropoxy)pyridine
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