2,4-Dinitrodiphenylamine

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Names

[ CAS No. ]:
961-68-2

[ Name ]:
2,4-Dinitrodiphenylamine

[Synonym ]:
2,4-DINITRO-N-PHENYLBENZENAMINE
2,4-Dinitro-N-phenylaniline
2,4-Dinitrodiphenylamine
Benzenamine, 2,4-dinitro-N-phenyl-
N1-phenyl-2,4-dinitroaniline
MFCD00007223
EINECS 213-508-4

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
413.8±35.0 °C at 760 mmHg

[ Melting Point ]:
159-161 °C(lit.)

[ Molecular Formula ]:
C12H9N3O4

[ Molecular Weight ]:
259.218

[ Flash Point ]:
204.1±25.9 °C

[ Exact Mass ]:
259.059296

[ PSA ]:
103.67000

[ LogP ]:
4.11

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.693

[ Stability ]:
Stable. Incompatible with strong bases, strong acids, strong oxidizing agents.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
JJ8825000
CHEMICAL NAME :
Diphenylamine, 2,4-dinitro-
CAS REGISTRY NUMBER :
961-68-2
BEILSTEIN REFERENCE NO. :
1996954
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C12-H9-N3-O4
MOLECULAR WEIGHT :
259.24
WISWESSER LINE NOTATION :
WNR CNW DMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#06394

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
JJ8825000

[ HS Code ]:
2921440000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Fluoro-2,4-dinitrobenzene
  • 2,4-Dinitrochlorobenzene
  • Cyclohexyl N-phenylsulfamate
  • 1,3-Dinitrobenzene
  • 2,4-dinitrophenyl N-phenylbenzimidate
  • GLYCOLANILIDE
  • 1-(2,4-dinitrophenyl)-4-methyl-3,5-dinitropyrazole
  • Benzene,1,1'-oxybis[2,4-dinitro- (9CI)

DownStream

  • 2,4-Dinitrophenol
  • 2-Nitro-4-aminodiphenylamine
  • 1,2-Benzenediamine,4-nitro-N1-phenyl-
  • 1,2,4-Benzenetriamine,N1-phenyl-
  • 2-nitrophenazine
  • 4-Methoxybenzenesulfonamide
  • potassium (2,4-dinitrophenyl)(phenyl)amide
  • 1-phenylbenzimidazol-5-amine
  • 5-nitro-1-phenylbenzimidazole

Customs

[ HS Code ]: 2921440000

[ Summary ]:
2921440000. diphenylamine and its derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%

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Reduction of Nitrated Diphenylamine Derivatives under Anaerobic Conditions.

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A simple and efficient anionic chromogenic chemosensor based on 2,4-dinitrodiphenylamine in dimethyl sulfoxide and in dimethyl sulfoxide-water mixtures.

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Solutions of 2,4-dinitrodiphenylamine (1) in dimethylsulfoxide (DMSO) are colorless but upon deprotonation they become red. Addition of various anionic species (HSO(4)(-), H(2)PO(4)(-), NO(3)(-), CN(-...


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Related Compounds

  • 2'-Methyl-2,4-dinitrodiphenylamine
  • 3'-methoxy-2,4-dinitrodiphenylamine
  • 2,4,6-Trichloro-3-(trimethylsilyl)pyridine
  • 2-iodo-3',4-dinitrodiphenylamine
  • 2-bromo-3',4-dinitrodiphenylamine
  • 2-[(4-methoxyphenyl)hydrazinylidene]-3-oxopentanal