2,4-Dinitroaniline

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Names

[ CAS No. ]:
97-02-9

[ Name ]:
2,4-Dinitroaniline

[Synonym ]:
Benzenamine, 2,4-dinitro-
Dinitroaniline,2,4
2,4-Nitroaniline
2,4-Dinitroaniline
Aniline,2,4-dinitro
2,4-Dinitroanilin
2,4-Dinitrobenzamine
2,4-Dinitraniline
1-amino-2,4-dinitrobenzene
WNR BZ ENW
2,4-dinitrobenzeneamine
2,4-Dinitroanilina
2,4-Di-nitroaniline
dinitro-2,4aniline
MFCD00007151
2,4-dinitrophenylamine
EINECS 202-553-5
2,4-Dinitrobenzenamine
o,p-dinitroaniline
2-nitro-4-fluorosulfonylaniline

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
400.6±25.0 °C at 760 mmHg

[ Melting Point ]:
177 °C

[ Molecular Formula ]:
C6H5N3O4

[ Molecular Weight ]:
183.122

[ Flash Point ]:
196.1±23.2 °C

[ Exact Mass ]:
183.028000

[ PSA ]:
117.66000

[ LogP ]:
2.22

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.679

[ Stability ]:
Stable. Incompatible with oxidizing agents. May decompose violently at elevated temperatures.

[ Water Solubility ]:
0.06 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BX9100000
CHEMICAL NAME :
Aniline, 2,4-dinitro-
CAS REGISTRY NUMBER :
97-02-9
BEILSTEIN REFERENCE NO. :
0982999
LAST UPDATED :
199710
DATA ITEMS CITED :
17
MOLECULAR FORMULA :
C6-H5-N3-O4
MOLECULAR WEIGHT :
183.14
WISWESSER LINE NOTATION :
WNR BZ ENW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
285 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
370 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
1050 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
1100 ug/m3/4H
SEX/DURATION :
female 1-7 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
17 mg/m3/4H
SEX/DURATION :
female 1-7 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea)
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
17 mg/m3/4H
SEX/DURATION :
female 1-7 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetal death

MUTATION DATA

TYPE OF TEST :
Unscheduled DNA synthesis
TEST SYSTEM :
Rodent - rat Liver
DOSE/DURATION :
50 umol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 221,263,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3 JAN 1993

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300-H310-H330-H373-H411

[ Precautionary Statements ]:
P260-P264-P273-P280-P284-P301 + P310

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T+:Verytoxic;N:Dangerous for the environment;

[ Risk Phrases ]:
R26/27/28;R33;R51/53

[ Safety Phrases ]:
S28-S36/37-S45-S61-S28A

[ RIDADR ]:
UN 1596 6.1/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
BX9100000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
29214210

Synthetic Route

Precursor & DownStream

Precursor

  • 2,4-Dinitrochlorobenzene
  • 4-Nitroaniline
  • 2,4-DINITROBENZENESULFONIC ACID
  • 1-(2,4-dinitrophenyl)piperidine
  • N-(2',4'-dinitrophenyl)-3-phenylpyridinium chloride
  • Dimethylamine
  • 1,3-Dinitrobenzene
  • (2,4-Dinitrophenyl)pyridinium chloride
  • Dibenzylamine
  • Ethanol,2-[(2,4-dinitrophenyl)amino]-

DownStream

  • N-[2-[(2-bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]acetamide
  • Bendamustine Hydrochloride
  • Benzenamine,2,4,6-trinitro-
  • Pigment Orange 5
  • 4-Nitroaniline
  • nitrobenzene
  • 3-chloro-4-iodonitrobenzene
  • 5-nitro-2,1,3-benzoxadiazole
  • 2,4-dinitrobenzenediazonium
  • 2,4-Dinitrophenol

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Simultaneous conduction of two- and three-phase hollow-fiber-based liquid-phase microextraction for the determination of aromatic amines in environmental water samples.

J. Chromatogr. A. 1216(5) , 756-62, (2009)

This paper describes a simultaneously performed two-/three-phase hollow-fiber-based liquid-phase microextraction (HF-LPME) method for the determination of aromatic amines with a wide range of pK(a) (-...

Simultaneous determination of five nitroaniline and dinitroaniline isomers in wastewaters by solid-phase extraction and high-performance liquid chromatography with ultraviolet detection.

Chemosphere 81(3) , 430-5, (2010)

A high-performance liquid chromatography (HPLC)-ultraviolet detection method, combined with solid-phase extraction (SPE), was developed for the determination of five nitroaniline and dinitroaniline is...

Liquid chromatographic determination of 2,4-dinitroaniline and 2-naphthol in D&C Orange No. 17.

J. Assoc. Off. Anal. Chem. 68(3) , 474-7, (1985)

A method is described for the determination of the intermediates in D&C Orange No. 17 by reverse phase liquid chromatography. The pigment is dissolved in boiling dioxane and then precipitated. The fil...


More Articles


Related Compounds

  • N-methyl-2,4-dinitroaniline
  • N-acetyl-2,4-dinitroaniline
  • 3-chloro-2,4-dinitroaniline
  • 3-methyl-2,4-dinitroaniline
  • 5-methoxy-2,4-dinitroaniline
  • N1-phenyl-2,4-dinitroaniline
  • 4-Methyl-5-(piperidin-2-yl)pyridin-2(1H)-one
  • Benzenemethanamine, 4-amino-3,5-dimethyl-I+/--(1-methylethyl)-
  • Methyl (3R)-3-amino-2,3-dihydrobenzo[3,4-B]furan-6-carboxylate
  • ethyl 2-({[3-(2-fluoro-4-methoxyphenyl)-6-oxopyridazin-1(6H)-yl]acetyl}amino)-4-methyl-1,3-thiazole-5-carboxylate
  • Methyl 3-bromo-4-hydroxy-5-(3-morpholino-3-oxopropanoyl)benzoate
  • 4-Chlorobenzaldehyde-formyl,2,3,5,6-d5
  • (S)-Ethyl piperazine-2-carboxylate
  • (R)-N-Methylpiperidin-3-amine
  • (2R,3R)-2-phenyloxolane-3-carboxylic acid
  • cis-1-Benzyl-4-(trifluoromethyl)pyrrolidine-3-carboxylic acid
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