Ethylene methacrylate

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Names

[ CAS No. ]:
97-90-5

[ Name ]:
Ethylene methacrylate

[Synonym ]:
Ethylene methacrylate
Ethylene dimethacrylate
Glycol dimethacrylate
Ethane-1,2-diyl bis(2-methylprop-2-enoate)
1UY1&VO2OVY1&U1
MFCD00008590
2-Propenoic acid, 2-methyl-, 1,2-ethanediyl ester
Ethyldiol methacrylate
Ethane-1,2-diyl bis(2-methylacrylate)
EINECS 202-617-2
1,2-Ethanediyl bis(2-methylacrylate)
Methacrylic acid ethylene ester
1,2-Ethanediol dimethacrylate
Ethylene glycol dimethacrylate

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
260.6±13.0 °C at 760 mmHg

[ Melting Point ]:
-40 °C

[ Molecular Formula ]:
C10H14O4

[ Molecular Weight ]:
198.216

[ Flash Point ]:
121.8±18.2 °C

[ Exact Mass ]:
198.089203

[ PSA ]:
52.60000

[ LogP ]:
2.78

[ Vapour density ]:
>1 (vs air)

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.449

[ Stability ]:
Unstable - may polymerize upon exposure to light. Incompatible with strong acids, strong oxidizing agents, strong bases.

[ Water Solubility ]:
soluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OZ4400000
CHEMICAL NAME :
Methacrylic acid, ethylene ester
CAS REGISTRY NUMBER :
97-90-5
BEILSTEIN REFERENCE NO. :
1776663
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C10-H14-O4
MOLECULAR WEIGHT :
198.24
WISWESSER LINE NOTATION :
1UY1&VO2OVY1&U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Mutation in mammalian somatic cells
TEST SYSTEM :
Rodent - mouse Lymphocyte
DOSE/DURATION :
5820 umol/L
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 17,264,1991 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M3204 No. of Facilities: 983 (estimated) No. of Industries: 3 No. of Occupations: 7 No. of Employees: 6295 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M3204 No. of Facilities: 562 (estimated) No. of Industries: 8 No. of Occupations: 14 No. of Employees: 9073 (estimated) No. of Female Employees: 3604 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H317-H335

[ Precautionary Statements ]:
P280-P304 + P340 + P312-P333 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R37;R43

[ Safety Phrases ]:
S24-S37

[ RIDADR ]:
UN3334 9

[ WGK Germany ]:
1

[ RTECS ]:
OZ4400000

[ Hazard Class ]:
9.0

[ HS Code ]:
2916140000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Ethylene glycol
  • Methyl methacrylate
  • ETHYLENE OXIDE
  • Methacrylic acid
  • Phenothiazine
  • 2-BROMOETHYL METHACRYLATE
  • 2-Bromoethanol
  • Diethyl ether
  • 3,3,4,5,5,5-hexafluoropentane-1,2-diol
  • Methacryloyl chloride

DownStream

  • Methacrylic acid
  • Allyl methacrylate
  • Terephthalaldehyde

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

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Related Compounds

  • Ethylene glycol methacrylate phosphate
  • ETHYLENE GLYCOL, ETHYL CARBONATE METHACRYLATE
  • Ethylene 2-(methacryloyloxy)ethyl phosphate
  • ethylene-2,2-dioxy-5-iodo-6-methylheptane
  • Ethylene Glycol Dibutyrate
  • Ethylene, 1,1,2,2-tetra-tert-butyl-
  • 2-{[5-ethyl-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)phenyl]formamido}butanoic acid
  • 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-{[2-(1H-1,2,4-triazol-1-yl)ethyl]carbamoyl}propanoic acid
  • (2R)-2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4,4-dimethylpentanamido]propanoic acid
  • (2R)-2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanamido]-3-methylbutanoic acid
  • (4R)-3-[3-cyclopropyl-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoyl]-1,3-thiazolidine-4-carboxylic acid
  • 4-[ethyl(2,2,2-trifluoroethyl)carbamoyl]-4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanoic acid
  • 2-{1-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanoyl]piperidin-3-yl}-2-methylpropanoic acid
  • 2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpropanamido]-4,4-difluorobutanoic acid
  • 3-(5-Bromo-2-chloro-4-pyrimidinyl)-7-nitro-1h-indole
  • 2-{1-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-fluorophenyl]-N-(prop-2-en-1-yl)formamido}acetic acid
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