Trichlorophenylsilane

Names

[ CAS No. ]:
98-13-5

[ Name ]:
Trichlorophenylsilane

[Synonym ]:
MFCD00000479
phenyl trichlorosilane
Phenyltrichlorosilane
Trichloro(phenyl)silane
UNII:M7199JL06M
Trichlorophenylsilane
Benzene, (trichlorosilyl)-
EINECS 202-640-8

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
201.0±9.0 °C at 760 mmHg

[ Melting Point ]:
-127°C

[ Molecular Formula ]:
C₆H₅Cl₃Si

[ Molecular Weight ]:
211.548

[ Flash Point ]:
87.5±13.4 °C

[ Exact Mass ]:
209.922607

[ LogP ]:
5.94

[ Vapour Pressure ]:
0.4±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.536

[ Water Solubility ]:
reacts

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VV6650000

CHEMICAL NAME :: Silane, trichlorophenyl-

CAS REGISTRY NUMBER :: 98-13-5

BEILSTEIN REFERENCE NO. :: 0508730

LAST UPDATED :: 199806

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C6-H5-Cl3-Si

MOLECULAR WEIGHT :: 211.55

WISWESSER LINE NOTATION :: G-SI-GGR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1228,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2390 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 330 mg/m3/2H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 3,23,1961

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04051

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 890 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84666 No. of Facilities: 8 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 272 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H312-H314-H330

[ Supplemental HS ]:
Corrosive to the respiratory tract., Reacts violently with water.

[ Precautionary Statements ]:
P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R21;R34

[ Safety Phrases ]:
S23-S26-S36/37/39-S45

[ RIDADR ]:
UN 1804 8/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
VV6650000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Tetrachlorosilane
Chlorobenzene
Dichlorodiphenylsilane
Phenylsilane
Trichlorosilane
Silicon
benzene
dichloro(o-chlorophenyl)phenylsilane
phenyl-sodium
Dichlorosilane

DownStream

tributoxy(phenyl)silane
1-Chlorobutane
phenyl-tris(2,2,2-trifluoroethoxy)silane
2-fluoro-1-methoxy-4-phenylbenzene
4-Biphenylylmethanol
Dichloro(diethoxy)silane
Chloro(triethoxy)silane
Phenyldiethoxychlorosilane
Dichloro(ethoxy)phenylsilane
trichloro(ethoxy)silane

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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