4-Hydroxyphenylarsonic Acid

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Names

[ CAS No. ]:
98-14-6

[ Name ]:
4-Hydroxyphenylarsonic Acid

[Synonym ]:
4-Hydroxyphenylarsonic Acid
Arsonic acid, As-(4-hydroxyphenyl)-
EINECS 202-641-3
(4-Hydroxyphenyl)arsonic acid

Chemical & Physical Properties

[ Boiling Point ]:
529.9±52.0 °C at 760 mmHg

[ Melting Point ]:
174 °C

[ Molecular Formula ]:
C6H7AsO4

[ Molecular Weight ]:
218.039

[ Flash Point ]:
288.3±27.2 °C

[ Exact Mass ]:
217.956024

[ PSA ]:
77.76000

[ LogP ]:
-0.74

[ Vapour Pressure ]:
0.0±1.5 mmHg at 25°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CY5075000
CHEMICAL NAME :
Benzenearsonic acid, p-hydroxy-
CAS REGISTRY NUMBER :
98-14-6
BEILSTEIN REFERENCE NO. :
2936785
LAST UPDATED :
199709
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C6-H7-As-O4
MOLECULAR WEIGHT :
218.05
WISWESSER LINE NOTATION :
Q-AS-QO&R DQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
450 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 63,122,1938
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 63,122,1938
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
90 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 63,122,1938
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04548 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994

Safety Information

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S22;S36/S37/S39

[ RIDADR ]:
UN 1554

[ Hazard Class ]:
6.1

[ HS Code ]:
2836400000

Synthetic Route

Precursor & DownStream

Precursor

  • arsenic acid
  • Phenol
  • Arsanilic acid
  • 4-HYDROXYBENZENEDIAZONIUM
  • 4-nitrosotoluene
  • 4-hydroxybenzenediazonium chloride

DownStream

  • Roxarsone
  • 2,4,6-Tribromophenol
  • Phenol,4-[2-(4-nitrophenyl)diazenyl]-
  • Arsonic acid,As-(3-amino-4-hydroxyphenyl)-
  • arsenic acid
  • 4-HYDROXY-3,5-DINITROBENZENEARSONIC ACID
  • [3-Amino-4-(2-hydroxyethoxy)phenyl]arsine oxide
  • [4-(2-oxopropoxy)phenyl]arsonic acid
  • 2-(4-arsono-2-nitro-phenoxy)acetic acid
  • [4-(2-hydroxyethoxy)-3-nitro-phenyl]arsonic acid

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%


Related Compounds

  • 3-Amino-4-hydroxyphenylarsonic acid
  • 3-formamido-4-hydroxyphenylarsonic acid
  • 3-acetylamino-4-hydroxyphenylarsonic acid
  • (4-acetamido-2-hydroxy-phenyl)arsonic acid
  • 4-octanoyloxybenzenesulfonic acid
  • 4-Cyanobenzoic acid