1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane

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Names

[ CAS No. ]:
98577-44-7

[ Name ]:
1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane

[Synonym ]:
1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane
MFCD00101445
Cyclopropane, 1,1-dibromo-2,2-bis(chloromethyl)-

Chemical & Physical Properties

[ Density]:
2.1±0.1 g/cm3

[ Boiling Point ]:
277.1±10.0 °C at 760 mmHg

[ Melting Point ]:
48-50ºC(lit.)

[ Molecular Formula ]:
C5H6Br2Cl2

[ Molecular Weight ]:
296.815

[ Flash Point ]:
134.5±9.1 °C

[ Exact Mass ]:
293.821320

[ LogP ]:
2.63

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.587

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2903890090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Chloro-2-(chloromethyl)-1-propene
  • Bromoform

DownStream

  • 1,3-diiodobicyclo[1.1.1]pentane
  • Methyl Vinyl Ether
  • methylenecyclobutane
  • bicyclo[1.1.1]pentane
  • Tricyclo[1.1.1.01,3]pentane

Customs

[ HS Code ]: 2903890090

[ Summary ]:
2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Crystalline arrays of pairs of molecular rotors: correlated motion, rotational barriers, and space-inversion symmetry breaking due to conformational mutations.

J. Am. Chem. Soc. 135(25) , 9366-9376, (2013)

The rod-like molecule bis((4-(4-pyridyl)ethynyl)bicyclo[2.2.2]oct-1-yl)buta-1,3-diyne, 1, contains two 1,4-bis(ethynyl)bicyclo[2.2.2]octane (BCO) chiral rotators linked by a diyne fragment and self-as...

Improved Preparations of 3-Chloro-2-(chloromethyl)-1-propene and 1, 1-Dibromo-2, 2-bis (chloromethyl) cyclopropane: Intermediates in the Synthesis of [1.1. 1] Propellane. Lynch KM and Dailey WP

J. Org. Chem. 60(14) , 4666-4668, (1995)

Concerning the synthesis of [1.1. 1] propellane. Belzner J, et al.

Chem. Ber. 122(2) , 397-398, (1989)


More Articles

Related Compounds

  • 1,1-dibromo-2,2-bis(chloromethyl)-3-propan-2-ylcyclopropane
  • 1-[2,2-dibromo-1-(4-methoxyphenyl)ethyl]-4-methoxybenzene
  • 1,1-dibromo-2-(2,2-dibromoethenyl)cyclopropane
  • 1,1-dibromo-2-(chloromethyl)cyclopropane
  • 1,1-dibromo-2,2-dimethyl-3-trimethylsilanyloxy-cyclopropane
  • 1,1-dibromo-2-(2,2,2-tribromoethyl)cyclopropane