tert-Butyl 2,2,2-trichloroacetimidate

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Names

[ CAS No. ]:
98946-18-0

[ Name ]:
tert-Butyl 2,2,2-trichloroacetimidate

[Synonym ]:
tert-Butyl 2,2,2-trichloroethanimidoate
tert-butyl 2,2,2-trichloroethanimidate
MFCD00237376
2-Methyl-2-propanyl 2,2,2-trichloroethanimidate
Ethanimidic acid, 2,2,2-trichloro-, 1,1-dimethylethyl ester

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
183.3±0.0 °C at 760 mmHg

[ Melting Point ]:
21 °C(lit.)

[ Molecular Formula ]:
C6H10Cl3NO

[ Molecular Weight ]:
218.509

[ Flash Point ]:
55.0±0.0 °C

[ Exact Mass ]:
216.982803

[ PSA ]:
33.08000

[ LogP ]:
2.83

[ Vapour Pressure ]:
1.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.480

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S37/39-S16-S36/37

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2925290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Trichloroacetonitrile
  • tert-Butanol
  • potassium t-butoxide

DownStream

  • z-thr(tbu)-otbu
  • z-thr-otbu
  • 1-TERT-BUTOXY-4-NITROBENZENE
  • Benzeneacetic acid, a-methyl-, 1,1-dimethylethyl ester
  • 1-Benzyl 3-tert-butyl piperidine-1,3-dicarboxylate
  • tert-butyl 2-bromohexanoate
  • tert-butyl (2S)-2,6-bis[(2-methylpropan-2-yl)oxycarbonylamino]hexanoate
  • 2-Methyl-2-propanyl bromoacetate
  • 2,2,2-Trichloroacetamide

Customs

[ HS Code ]: 2925290090

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Palmitoylation of plakophilin is required for desmosome assembly.

J. Cell Sci. 127(Pt 17) , 3782-93, (2014)

Desmosomes are prominent adhesive junctions found in various epithelial tissues. The cytoplasmic domains of desmosomal cadherins interact with a host of desmosomal plaque proteins, including plakophil...

Biocompatible click chemistry enabled compartment-specific pH measurement inside E. coli.

Nat. Commun. 5 , 4981, (2014)

Bioorthogonal reactions, especially the Cu(I)-catalysed azide-alkyne cycloaddition, have revolutionized our ability to label and manipulate biomolecules under living conditions. The cytotoxicity of Cu...

A. Armstrong et al.

Tetrahedron Lett. 29 , 2483, (1988)


More Articles

Related Compounds

  • tert-butyl 2,2,2-trichloroacetimidate
  • tert-butyl 2,2,2-tribromoacetate
  • tert-butyl 2-(2,2,2-trifluoroacetamido)hexanoate
  • tert-butyl 2-[[2-[[2-[(2-nitrophenyl)sulfanylamino]-3-tritylsulfanyl-propanoyl]amino]-3-phenyl-propanoyl]amino]acetate
  • 1-tert-butyl-2-[2-(2-tert-butyl-6-methylphenyl)propan-2-yl]-3-methylbenzene
  • di-(tert-butyl) 2-(2,2-dimethyl-4H-1,3-benzodioxin-6-yl)-2-oxoethyliminodicarbonate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • N-[1-(3-Methoxypropyl)-2-oxo-1,2-dihydrobenzo[cd]indol-6-yl]-1-(thiophen-2-ylsulfonyl)piperidine-2-carboxamide
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4-(Methylamino)butane-1,2-diol hydrochloride
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine