tert-Butyl 2,2,2-trichloroacetimidate

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Names

[ Name ]:
tert-Butyl 2,2,2-trichloroacetimidate

[Synonym ]:
tert-Butyl 2,2,2-trichloroethanimidoate
tert-butyl 2,2,2-trichloroethanimidate
MFCD00237376
2-Methyl-2-propanyl 2,2,2-trichloroethanimidate
Ethanimidic acid, 2,2,2-trichloro-, 1,1-dimethylethyl ester

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
183.3±0.0 °C at 760 mmHg

[ Melting Point ]:
21 °C(lit.)

[ Molecular Formula ]:
C₆H₁₀Cl₃NO

[ Molecular Weight ]:
218.509

[ Flash Point ]:
55.0±0.0 °C

[ Exact Mass ]:
216.982803

[ PSA ]:
33.08000

[ LogP ]:
2.83

[ Vapour Pressure ]:
1.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.480

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S37/39-S16-S36/37

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2925290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Trichloroacetonitrile
tert-Butanol
potassium t-butoxide

DownStream

z-thr(tbu)-otbu
z-thr-otbu
1-TERT-BUTOXY-4-NITROBENZENE
Benzeneacetic acid, a-methyl-, 1,1-dimethylethyl ester
1-Benzyl 3-tert-butyl piperidine-1,3-dicarboxylate
tert-butyl 2-bromohexanoate
tert-butyl (2S)-2,6-bis[(2-methylpropan-2-yl)oxycarbonylamino]hexanoate
2-Methyl-2-propanyl bromoacetate
2,2,2-Trichloroacetamide

Customs

[ HS Code ]: 2925290090

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Palmitoylation of plakophilin is required for desmosome assembly.

J. Cell Sci. 127(Pt 17) , 3782-93, (2014)

Desmosomes are prominent adhesive junctions found in various epithelial tissues. The cytoplasmic domains of desmosomal cadherins interact with a host of desmosomal plaque proteins, including plakophil...

Biocompatible click chemistry enabled compartment-specific pH measurement inside E. coli.

Nat. Commun. 5 , 4981, (2014)

Bioorthogonal reactions, especially the Cu(I)-catalysed azide-alkyne cycloaddition, have revolutionized our ability to label and manipulate biomolecules under living conditions. The cytotoxicity of Cu...

A. Armstrong et al.

Tetrahedron Lett. 29 , 2483, (1988)

tert-butyl 2,2,2-trichloroacetimidate
tert-butyl 2,2,2-tribromoacetate
tert-butyl 2-(2,2,2-trifluoroacetamido)hexanoate
tert-butyl 2-[[2-[[2-[(2-nitrophenyl)sulfanylamino]-3-tritylsulfanyl-propanoyl]amino]-3-phenyl-propanoyl]amino]acetate
1-tert-butyl-2-[2-(2-tert-butyl-6-methylphenyl)propan-2-yl]-3-methylbenzene
di-(tert-butyl) 2-(2,2-dimethyl-4H-1,3-benzodioxin-6-yl)-2-oxoethyliminodicarbonate
N-[(2-fluoro-3-nitrophenyl)methyl]hydroxylamine
3,3-Difluoro-3-(pyrimidin-2-yl)propan-1-amine
(3-(2-Bromo-4-(methoxymethoxy)phenyl)prop-1-yn-1-yl)triisopropylsilane
Ethyl 2-amino-4-hydroxy-5-methoxypentanoate
Ethyl 2-amino-5-chloro-5,5-difluoropentanoate
4-Methyl-2-(2-nitroethenyl)pyridine
3-[(4-Bromo-2-nitrophenyl)methyl]azetidine
4-(2-Chloro-5-nitrophenyl)butan-1-amine
Methyl 4-(3-amino-2-hydroxypropyl)benzoate
N-(3-azabicyclo[3.1.0]hex-2-en-2-yl)hydroxylamine

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