alpha-Terpinene

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Names

[ CAS No. ]:
99-86-5

[ Name ]:
alpha-Terpinene

[Synonym ]:
a-Terpinene
α-Terpinene
Terpilene
Terpinene
α -Terpinene
alpha-terpinene
p-Mentha-1,3-diene
1-methyl-4-isopropyl-1,3-cyclohexadiene
1-methyl-4-propan-2-yl-cyclohexa-1,3-diene
L6U CUTJ AY1&1 D1
1-Isopropyl-4-methyl-1,3-cyclohexadiene
1-methyl-4-propan-2-ylcyclohexa-1,3-diene
1-Methyl-4-(propan-2-yl)cyclohexa-1,3-diene
1-Isopropyl-4-methylcyclohexa-1,3-diene
1,3-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-
MFCD00001534
EINECS 202-795-1
MFCD0001534
FEMA No. 3558

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
174.1±0.0 °C at 760 mmHg

[ Melting Point ]:
-59.03°C (estimate)

[ Molecular Formula ]:
C10H16

[ Molecular Weight ]:
136.234

[ Flash Point ]:
46.1±0.0 °C

[ Exact Mass ]:
136.125198

[ LogP ]:
4.53

[ Appearance of Characters ]:
Liquid | Clear colorless to light yellow

[ Vapour Pressure ]:
1.6±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.476

[ Storage condition ]:
−20°C

[ Water Solubility ]:
95% ethanol: soluble1ml/2ml, clear, colorless | Soluble in ether, alcohol, and ethanol (100 mg/ml). Insoluble in water.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OS8060000
CHEMICAL NAME :
p-Mentha-1,3-diene
CAS REGISTRY NUMBER :
99-86-5
LAST UPDATED :
199709
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C10-H16
MOLECULAR WEIGHT :
136.26
WISWESSER LINE NOTATION :
L6U CUTJ AY1&1 D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1680 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 14,873,1976 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
600 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system Reproductive - Effects on Newborn - behavioral
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 34,477,1996
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
2500 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Maternal Effects - other effects Reproductive - Fertility - female fertility index (e.g. # females pregnant per # sperm positive females; # females pregnant per # females mated) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 34,477,1996 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5037 No. of Facilities: 1539 (estimated) No. of Industries: 29 No. of Occupations: 27 No. of Employees: 40804 (estimated) No. of Female Employees: 9980 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302-H315-H319-H335-H411-H413

[ Precautionary Statements ]:
P210-P261-P273-P280-P301 + P312 + P330-P304 + P340 + P312-P305 + P351 + P338-P337 + P313-P403 + P235

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn,N

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
26-36/37-61-62

[ RIDADR ]:
UN 2319 3/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
OS8060000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
3805909000

Synthetic Route

Precursor & DownStream

Precursor

  • Beta-pinene
  • Terpin Monohydrate
  • limonene
  • Terpineol
  • Terpinolene
  • Alpha-pinene
  • γ-terpinene
  • (+)-Limonene
  • (1S)-(-)-Alpha-Pinene

DownStream

  • p-cymene
  • (4-Isopropyl-1,3-cyclohexadien-1-yl)methanol
  • 4-Isopropylbenzoic acid
  • Nα-glycyl[8-lysine]vasopressin
  • Cuminol
  • Ascaridole
  • (+/-)-1,2,3,4-diepoxy-cis-p-menthane
  • 3-hydroperoxy-4-isopropyl-1-methylcyclohexa-1,4-diene

Customs

[ HS Code ]: 2902199090

[ Summary ]:
2902199090 other cyclanes, cyclenes and cyclotherpenes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

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