1-(4-Bromophenyl)ethanone

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Names

[ CAS No. ]:
99-90-1

[ Name ]:
1-(4-Bromophenyl)ethanone

[Synonym ]:
1-(4-bromophenyl)ethan-1-one
4'-Bromoacetophenone
Methyl p-bromophenyl ketone
Ethanone, 1- (4-bromophenyl)-
Ethanone, 1-(4-bromophenyl)-
1-(4-Bromophenyl)ethanone
1-(4-Bromo-phenyl)-ethanone
4′-bromoacetophenone
para-bromoacetophenon
para-bromoacetophenone
p-Bromophenyl methyl ketone
Acetophenone, 4'-bromo-
MFCD00000200
EINECS 202-783-6
4-bromoacetophenone

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
259.9±23.0 °C at 760 mmHg

[ Melting Point ]:
108-110 °C(lit.)

[ Molecular Formula ]:
C8H7BrO

[ Molecular Weight ]:
199.04

[ Flash Point ]:
94.3±9.9 °C

[ Exact Mass ]:
197.968018

[ PSA ]:
17.07000

[ LogP ]:
2.43

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.554

[ Water Solubility ]:
methanol: 0.1 g/mL, clear

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H315-H319-H334-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338-P342 + P311

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S26-S36/37/39-S45-S22-S36/37

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
AM6950000

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
29147090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-(4-Bromophenyl)ethanol
  • 4-Acetylphenylboronic acid
  • 1-bromo-4-(1-bromethyl)-benzene
  • 4-Bromophenylacetylene
  • 4-Bromostyrene
  • carbon monoxide
  • 1-Bromo-4-iodobenzene
  • METHYLLITHIUM
  • 4-Bromophenylboronic Acid
  • Acetonitrile

DownStream

  • 1-(4-bromophenyl)-5-phenylpent-4-yne-1,3-dione
  • 1-(4-bromophenyl)-2-(4-nitrophenoxy)ethanone
  • 1-(3,4-Dibromophenyl)ethanone
  • 3,4,5-TRIBROMOACETOPHENONE
  • 1-[4-(3-chloro-4-hydroxyphenyl)phenyl]ethanone
  • [2-(4-bromophenyl)-2-oxoethyl] formate
  • 1-[4-(2-methyl-1,3-dioxolan-2-yl)phenyl]ethanone
  • 2-(4-bromophenyl)-2,5,5-trimethyl-1,3-dioxane
  • p-Heptylacetophenone

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Screening of microorganisms producing cold-active oxidoreductases to be applied in enantioselective alcohol oxidation. An Antarctic survey.

Mar. Drugs 9 , 889-905, (2011)

Several microorganisms were isolated from soil/sediment samples of Antarctic Peninsula. The enrichment technique using (RS)-1-(phenyl)ethanol as a carbon source allowed us to isolate 232 psychrophile/...

Magnetic nanoparticle-supported proline as a recyclable and recoverable ligand for the CuI catalyzed arylation of nitrogen nucleophiles.

Chem. Commun. (Camb.) (45) , 4809-11, (2007)

Magnetic nanoparticle-supported proline ligand was prepared and used for the CuI catalyzed Ullmann-type coupling reactions of aryl/heteroaryl bromides with various nitrogen heterocycles to form the co...

Mechanochemical solid-state Suzuki reactions using an in situ generated base.

ChemSusChem 1(7) , 622-5, (2008)


More Articles

Related Compounds

  • 2-Bromo-1-(4-bromophenyl)ethanone
  • 2-amino-1-(4-bromophenyl)ethanone
  • 2-azido-1-(4-bromophenyl)ethanone
  • 2-anilino-1-(4-bromophenyl)ethanone
  • 1-(4-bromophenyl)ethanone O-tosyl oxime
  • 2-bromo-1-(4-bromophenyl)ethanone oxime
  • 5-[1-(Aminomethyl)-3,3-difluorocyclobutyl]-3-methoxybenzene-1,2-diol
  • 3-{5H,6H,7H,8H-imidazo[1,2-a]pyridin-2-yloxy}pyrrolidine
  • tert-butyl N-[1-(3,3,3-trifluoro-2-oxopropyl)cyclobutyl]carbamate
  • 2-(2,5-Difluoro-4-methylphenyl)cyclopropane-1-carboxylic acid
  • rac-(1R,3S)-3-{6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl}-2,2-dimethylcyclopropan-1-amine
  • 3-(1H-indazol-7-yl)oxolane-2,5-dione
  • (1R)-2-amino-1-{3H-[1,2,3]triazolo[4,5-b]pyridin-6-yl}ethan-1-ol
  • tert-Butyl ((1R,2R)-2-((tert-butyldimethylsilyl)oxy)-4-hydroxycyclopentyl)carbamate
  • 1-(5-Nitropyridin-2-yl)-3-oxocyclobutane-1-carboxylic acid
  • tert-butyl N-{3-[(5-hydroxypentyl)oxy]-4-methylphenyl}carbamate
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