Tributylethynylstannane

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Names

[ CAS No. ]:
994-89-8

[ Name ]:
Tributylethynylstannane

[Synonym ]:
MFCD00009420
Stannane, tributylethynyl-
Tributyl(ethynyl)stannane

Chemical & Physical Properties

[ Density]:
1.089 g/mL at 25 °C(lit.)

[ Boiling Point ]:
281.6±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C14H28Sn

[ Molecular Weight ]:
315.082

[ Flash Point ]:
136.7±9.7 °C

[ Exact Mass ]:
316.121307

[ LogP ]:
9.26

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.476(lit.)

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H312-H315-H319-H372-H400

[ Precautionary Statements ]:
P273-P280-P301 + P310-P305 + P351 + P338-P314

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;N: Dangerous for the environment;

[ Risk Phrases ]:
R21

[ Safety Phrases ]:
S35-S36/37/39-S45-S60-S61

[ RIDADR ]:
UN 2788 6.1/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2931900090

Synthetic Route

Precursor & DownStream

Precursor

  • Chlorotributyltin
  • sodium acetylide
  • sodium monoacetylide
  • Ethynylmagnesium chloride
  • Tributyltin oxide
  • Acetylene
  • Stannane,tributylhydroxy-
  • Phenylethynyltri-n-Butyltin
  • N-ethyl-N-tributylstannylethanamine
  • Phenylpropiolsaeure-tri-n-butylstannylester

DownStream

  • ethynyl(trimethyl)stannane
  • Phenylethynyltri-n-Butyltin
  • iodoethyne
  • 3-Ethynylbenzonitrile
  • Phenylacetylene
  • 1,4-Diethynylbenzene
  • ethynyl(phenyl)iodonium triflate
  • Tributyltin oxide
  • Tributyltin hydride
  • 4-iodo-2-pyridin-2-ylpyridine

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

J. Chem. Soc. Perkin Trans. I , 1657, (1993)

Synlett , 557, (1994)

Acta Chem. Scand. 48 , 61, (1994)


More Articles


Related Compounds

  • Tributylethynylstannane
  • Tributylethynylstannane
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 4-(2,2,2-Trifluoroethoxy)but-1-yne
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Bromo-1-(2,2-dimethylthiolan-3-yl)ethan-1-ol
  • 5-bromo-N-methyl-N-(pyrrolidin-3-yl)pyrazin-2-amine
  • tert-butyl N-[2-(4-ethenylphenyl)ethyl]carbamate
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide