Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II)

Names

[ CAS No. ]:
99604-67-8

[ Name ]:
Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II)

[Synonym ]:
MFCD08457650

Chemical & Physical Properties

[ Molecular Formula ]:
C₁₆H₂₄F₆N₃PRu

[ Molecular Weight ]:
504.41600

[ Exact Mass ]:
505.06600

[ PSA ]:
84.96000

[ LogP ]:
7.94404

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

Articles

Markovnikov alkyne hydrosilylation catalyzed by ruthenium complexes.

J. Am. Chem. Soc. 123 , 12726, (2001)

Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition.

J. Am. Chem. Soc. 127 , 17644, (2005)

The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access to alpha-vinylsilane products with good regioselectivity. Deuterium la...