Methyl 4-boronobenzoate

Names

[ Name ]:
Methyl 4-boronobenzoate

[Synonym ]:
Benzoic acid, 4-borono-, methyl ester
[4-(Methoxycarbonyl)phenyl]boronic acid
MFCD01632203
Methyl 4-boronobenzoate
(4-methoxycarbonylphenyl)boronic acid

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
345.8±44.0 °C at 760 mmHg

[ Melting Point ]:
197-200 °C(lit.)

[ Molecular Formula ]:
C₈H₉BO₄

[ Molecular Weight ]:
179.97

[ Flash Point ]:
162.9±28.4 °C

[ Exact Mass ]:
180.059387

[ PSA ]:
66.76000

[ LogP ]:
1.57

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.533

[ Storage condition ]:
0-6°C

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Methanol
p-Boronobenzoic acid
4-Tolylboronic acid
Methyl 4-iodobenzoate
(Trimethylsilyl)diazomethane
Sulfuric acid
Dimethyl sulfate
Methyl 4-bromobenzoate
potassium (4-methoxycarbonylphenyl)trifluoroborate

DownStream

4'-(METHOXYCARBONYL)-[1,1'-BIPHENYL]-4-CARBOXYLIC ACID
METHYL 4-(PYRIDIN-4-YL)BENZOATE
methyl 4-phenylselanylbenzoate
Methyl 4-(5-formylfuran-2-yl)benzoate
Methyl 4'-methylbiphenyl-4-carboxylate
methyl 4-thiophen-2-ylbenzoate
Methyl 4-fluorobenzoate
Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
Methyl 4-azidobenzoate
Methyl 4-hydroxybenzoate

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

ipso-Nitration of arylboronic acids with bismuth nitrate and perdisulfate.

Org. Lett. 7th ed., 14 , 1736-1739, (2012)

An efficient and one pot synthetic method of ipso-nitration of arylboronic acids has been developed. The high efficiency, general applicability, and broader substrate scope including heterocycles and ...

Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones.

Chem. Commun. (Camb.) 36th ed., 48 , 4332-4334, (2012)

A novel catalytic method for synthesizing 4-aryl-2-quinolinones is reported. The process involves two mechanistically independent, sequential Pd(II)-catalyzed reactions--the oxidative Heck reaction an...

Pt nanoparticles@photoactive metal-organic frameworks: efficient hydrogen evolution via synergistic photoexcitation and electron injection.

J. Am. Chem. Soc. 17th ed., 134 , 7211-7214, (2012)

Pt nanoparticles of 2-3 nm and 5-6 nm in diameter were loaded into stable, porous, and phosphorescent metal-organic frameworks (MOFs 1 and 2) built from [Ir(ppy)(2)(bpy)](+)-derived dicarboxylate liga...

methyl 4-hexadecoxybenzoate
methyl 4,5-dibromohex-2-enoate
METHYL 4-(4-(3-(PYRIDIN-2-YL)-1H-PYRAZOL-4-YL)PYRIDIN-2-YL)BENZOATE
methyl 4-[4-(4-chlorophenyl)-4-hydroxypiperidin-1-yl]butanoate
methyl 4-[(4-aminophenyl)carbamoyl]benzoate
methyl 4-formyl-5,5-diphenylpenta-2,4-dienoate
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine
4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine