Triethoxysilane

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Names

[ CAS No. ]:
998-30-1

[ Name ]:
Triethoxysilane

[Synonym ]:
MFCD00009061
5,6-epoxyhexyltriethoxysilane
EINECS 213-650-7
triethoxy-silane
Silane,triethoxy
Triethoxysilicane
triethoxy-silan
Silane, triethoxy-
Triethoxysilane
3-piperazinopropyltriethoxysilane
4-bromooctafluorobutanetriethoxysilane
TRIES
CT2500

Chemical & Physical Properties

[ Density]:
0.89 g/mL at 25 °C(lit.)

[ Boiling Point ]:
133.5±0.0 °C at 760 mmHg

[ Melting Point ]:
-170°C

[ Molecular Formula ]:
C6H16O3Si

[ Molecular Weight ]:
164.275

[ Flash Point ]:
29.2±18.7 °C

[ Exact Mass ]:
164.086868

[ PSA ]:
27.69000

[ LogP ]:
4.70

[ Vapour Pressure ]:
10.4±0.2 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.377(lit.)

[ Storage condition ]:
Store at 0-5°C

[ Stability ]:
Stable, but moisture sensitive. Flammable. Incompatible with strong oxidizing agents, strong acids, strong bases.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VV6682000
CHEMICAL NAME :
Silane, triethoxy-
CAS REGISTRY NUMBER :
998-30-1
BEILSTEIN REFERENCE NO. :
1738989
LAST UPDATED :
199710
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C6-H16-O3-Si
MOLECULAR WEIGHT :
164.31
WISWESSER LINE NOTATION :
2O-SI-O2&O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
500 mg/m3/2H
TOXIC EFFECTS :
Behavioral - ataxia Lungs, Thorax, or Respiration - acute pulmonary edema Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 5,192,1963
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/m3/2H
TOXIC EFFECTS :
Behavioral - ataxia Lungs, Thorax, or Respiration - acute pulmonary edema Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 5,192,1963
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00018 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
20 mg/m3/3H/22W-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Liver - liver function tests impaired Blood - changes in leukocyte (WBC) count
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 5,192,1963

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314-H330

[ Precautionary Statements ]:
P260-P280-P284-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;C:Corrosive;

[ Risk Phrases ]:
R10;R23/24/25;R34

[ Safety Phrases ]:
S26-S28-S36/37/39-S45

[ RIDADR ]:
UN 3384 6.1/PG 1

[ WGK Germany ]:
3

[ RTECS ]:
VV6682000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

Synthetic Route

Precursor & DownStream

Precursor

  • Ethanol
  • Silicon
  • Trichlorosilane
  • ethene
  • Ethoxy(trimethyl)silane
  • Triethyl orthoformate
  • trimethyl-silanyl-ammonium, chloride
  • benzene
  • butoxy-dichloro-silane

DownStream

  • phenethyltrimethoxysilane
  • Acetoxymethyltriethoxysilane
  • ethyl acetate
  • Chloro(triethoxy)silane
  • (3-Chloropropyl)triethoxysilane
  • Tetraethyl orthosilicate
  • (3-chloropropyl)-diethoxy-chlorosilane
  • propyltriethoxysilane
  • Ethyl benzoate

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Related Compounds

  • triethoxysilane
  • octyltriethoxysilane
  • Methyltriethoxysilane
  • m-PEG5-triethoxysilane
  • i-butyltriethoxysilane
  • 2-BUTYL-TRIETHOXYSILANE
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  • 4-bromo-N-(3-hydroxyphenyl)-2,5-dimethylbenzenesulfonamide
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
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