Chemistry: A European Journal 2015-07-06

Heterolysis of Dihydrogen by Silver Alkoxides and Fluorides.

Brandon K Tate, Jenna T Nguyen, John Bacsa, Joseph P Sadighi

文献索引：Chemistry 21 , 10160-9, (2015)

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摘要

Alkoxide-bridged disilver cations react with dihydrogen to form hydride-bridged cations, releasing free alcohol. Hydrogenolysis of neutral silver fluorides affords hydride-bridged disilver cations as their bifluoride salts. These reactions proceed most efficiently when the supporting ligands are expanded N-heterocyclic carbenes (NHCs) derived from 6- and 7-membered cyclic amidinium salts. Kinetics studies show that silver fluoride hydrogenolysis is first-order in both silver and dihydrogen. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

相关化合物

  • 重水
  • 乙腈
  • 二氯甲烷
  • 氢化铝锂
  • 四氢呋喃
  • 氘
  • 苯
  • 叔戊醇钠
  • 钙
  • 甲苯

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