Acta Crystallographica Section E 2009-01-01

[1-(1-Adamantylamino)ethyl-idene]oxonium methane-sulfonate.

Robert Vícha, Marek Nečas, Zuzana Kozubková, Milan Potáček

文献索引：Acta Crystallogr. Sect. E Struct. Rep. Online 65(Pt 6) , o1307, (2009)

全文：HTML全文

摘要

In the title salt, C(12)H(20)NO(+)·CH(3)SO(3) (-), the [1-(1-adamantyl-amino)ethyl-idene]oxonium cations and methane-sulfonate anions are linked into chains along the a axis via O-H⋯O and N-H⋯O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) Å. In comparison with related structures, the carbonyl C=O bond is slightly elongated [1.249 (2) Å], whereas the amide C-N bond is shortened [1.292 (2) Å].

相关化合物

  • 亚硫酸氢钠穿心莲内...

相关文献：

Electrosynthetic reduction of 1-iodoadamantane forming 1,1'-biadamantane and adamantane in aprotic solvents: insonation switches the mechanism from dimerisation to exclusive monomer formation.

2007-07-01

[Ultrason. Sonochem. 14(5) , 502-8, (2007)]

Fluorescent quenching of the 2-naphthoxide anion by aliphatic and aromatic halides. Mechanism and consequences of electron transfer reactions.

2003-03-21

[J. Org. Chem. 68(6) , 2362-8, (2003)]

Regiochemistry of the photostimulated reaction of the phthalimide anion with 1-iodoadamantane and tert-butylmercury chloride by the S(RN)1 mechanism.

2002-02-08

[J. Org. Chem. 67(3) , 1012-5, (2002)]

[J. Am. Chem. Soc. 115 , 1187, (1993)]

[Synlett , 143, (1993)]

更多文献...