Kinetics and mechanism of propachlor reductive transformation through nucleophilic substitution by dithionite
C.S. Liu, K. Shih, L. Wei, F. Wang, F.B. Li, C.S. Liu, K. Shih, L. Wei, F. Wang, F.B. Li, C.S. Liu, K. Shih, L. Wei, F. Wang, F.B. Li
文献索引:Chemosphere 85(9) , 1438-43, (2011)
全文:HTML全文
摘要
Highlights ► The reductive dechlorination of propachlor was efficiently achieved by dithionite. ► The transformation of propachlor initiated by dithionite follows second-order kinetics. ► Dechlorination was found to be the first and necessary step of propachlor transformation initiated by dithionite. ► Propachlor nucleophilic substitution by dithionite was confirmed as the S N2 mechanism.
相关化合物
相关文献:
1999-01-01
[Cell Biol. Toxicol. 15(5) , 325-32, (1999)]
2007-01-01
[Rapid Commun. Mass Spectrom. 21(24) , 4017-22, (2007)]
2005-10-01
[Environ. Toxicol. Chem. 24(10) , 2401-9, (2005)]
2009-06-01
[Food Chem. Toxicol. 47(6) , 1051-7, (2009)]
2007-01-01
[Water Sci. Technol. 55(3) , 37-44, (2007)]