Demixing of severely overlapped ¹H NMR resonances and interpretation of anomalous intensity pattern of dipolar coupled A₃ spins in a weakly aligning medium.

Nilamoni Nath, N Suryaprakash

文献索引：J. Magn. Reson. 207(2) , 190-6, (2010)

全文：HTML全文

摘要

We report a single (13)C spin edited selective proton-proton correlation experiment to decipher overcrowded (13)C coupled proton NMR spectra of weakly dipolar coupled spin systems. The experiment unravels the masked (13)C satellites in proton spectrum and permits the measurement of one bond carbon-proton residual dipolar couplings in I(3)S and for each diastereotopic proton in I(2)S groups. It also provides all the possible homonuclear proton-proton residual couplings which are otherwise difficult to extract from the broad and featureless one dimensional (1)H spectrum, in addition to enantiodifferentiation in a chiral molecule. Employment of heteronuclear ((13)C) decoupling in the evolution period results in complete demixing of overlapped signals from enantiomers. The observed anomalous intensity pattern in strongly dipolar coupled methyl protons in methyl selective correlation experiment has been interpreted using polarization operator formalism.Copyright © 2010 Elsevier Inc. All rights reserved.

相关化合物

  • B-丁内酯
  • 3-氯丙酸
  • 碳酸丙烯酯

相关文献：

Involvement of catalytic amino acid residues in enzyme-catalyzed polymerization for the synthesis of polyesters.

2001-07-01

[Biomacromolecules 2(2) , 541-4, (2001)]

Ring-opening polymerisation of beta-butyrolactone catalysed by distannoxane complexes: study of the mechanism.

1999-01-01

[Int. J. Biol. Macromol. 25(1-3) , 237-45, (1999)]

Novel synthesis of functionalized poly(3-hydroxybutanoic acid) and its copolymers.

1999-01-01

[Int. J. Biol. Macromol. 25(1-3) , 247-53, (1999)]

Water-soluble L-alanine and related oligopeptide conjugates with poly[(R,S)-3-hydroxybutanoic acid] oligomers, synthesis and structural studies by means of electrospray ionization multistage mass spectrometry.

2001-01-01

[J. Biomater. Sci. Polym. Ed. 12(3) , 297-305, (2001)]

Highly controlled immortal polymerization of β-butyrolactone by a dinuclear indium catalyst.

2012-07-11

[Chem. Commun. (Camb.) 48(54) , 6806-8, (2012)]

更多文献...