Forensic Science International 2000-03-27

Study of the reaction mechanism of 1,8-diazafluoren-9-one with the amino acid, L-alanine.

D Wilkinson

文献索引:Forensic Sci. Int. 109 , 87-103, (2000)

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摘要

This paper describes the study of the reaction between 1, 8-diazafluoren-9-one (DFO) with the amino acid L-alanine in methyl alcohol. Particular interest was paid to the possible role of the solvent which appears to react with the DFO to form a hemiketal that is the reactive species. A potential reaction pathway is proposed based on the current data collected. The reaction intermediates and products were identified by a variety of spectroscopic methods including mass spectrometry (MS), nuclear magnetic resonance (NMR) spectroscopy, and X-ray crystallography.


相关化合物

  • 1,8-二氮杂-9-芴酮

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