Synthesis and reactivity of an isolable cobalt(I) complex containing a β-diketiminate-based acyclic tetradentate ligand.
Elodie E Marlier, Bridget A Ulrich, Kristopher McNeill
文献索引:Inorg. Chem. 51(4) , 2079-85, (2012)
全文:HTML全文
摘要
A model for cobalamin was synthesized using a new monoanionic tetradentate nitrogen donor ligand; 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine (Tol-BDI((2-pp)2)H) (1), which utilizes isopropylpyridines as pendant arms on a β-diketiminate (BDI) backbone. During the synthesis of 1, the rearrangement product, Tol-BDI((2-pp)(4-pp))H (2) was observed. Metalation of 1 with zinc iodide and cobalt chloride yielded the corresponding Tol-BDI((2-pp)2)ZnI (3) and Tol-BDI((2-pp)2)CoCl (4) complexes. The redox properties of 4 in comparison to cobalamin were examined through electrochemical studies. Electrochemical and bulk reduction of complex 4 gave a diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co (5). Reactivity of 5 toward C-X bonds was investigated using methyl iodide and 1-iodo-2-(trimethylsilyl)acetylene, yielding Tol-BDI((2-pp)2)Co(CH(3))I and Tol-BDI((2-pp)2)Co(C(2)Si(CH(3))(3))I respectively. Synthesis and characterization details for these complexes, including the crystal structure of 3, are reported.
相关化合物
相关文献:
Novel polyacetylenes containing pendant 1-pyrenyl groups: synthesis, characterization, and thermal and optical properties. Rivera E, et al.
[Polymer 43(19) , 5059-68, (2009)]