Journal of Chromatography A 1998-10-16

Capillary ion electrophoresis screening of nerve agent degradation products in environmental samples using conductivity detection.

T E Rosso, P C Bossle

文献索引：J. Chromatogr. A. 824(1) , 125-34, (1998)

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摘要

A method of detecting signature methylphosphonic acid (MPA) breakdown products of V and G nerve agents in environmental samples was developed using capillary ion electrophoresis with conductivity detection. The electrolyte (30 mM L-histidine, 30 mM 2-(N-morpholino)ethanesulfonic acid, 0.7 mM tetradecyltrimethylammonium hydroxide, and 0.03 weight% Triton X-100) allowed baseline separation of MPA, ethyl methylphosphonic acid (EMPA), isopropyl methylphosphonic acid (IMPA), and pinacolyl methylphosphonic acid (PMPA) in less than 10 min. Detector response was linear in the 6-60 micrograms/ml concentration range (correlation coefficient = 0.99) with a detection limit around 6 micrograms/ml. The application of this method for screening MPA, EMPA, IMPA, and PMPA in surface water, groundwater, and soil extracts is demonstrated.

相关化合物

  • Isopropyl methylph...
  • 甲基磷酸乙酯
  • 甲基磷酸片呐酯

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