Chemistry: A European Journal
2015-01-07
Graphitic carbon nitride polymer as a recyclable photoredox catalyst for fluoroalkylation of arenes.
Moritz Baar, Siegfried Blechert
文献索引:Chemistry 21(2) , 526-30, (2015)
全文:HTML全文
摘要
Heterogeneous catalysis for trifluoromethylations and perfluoroalkylations has been performed. Through the usage of cheap, metal-free and recyclable mesoporous graphitic carbon nitride (mpg-CN) it was possible to fluoroalkylate various arenes by the reductive activation of sulfonyl chlorides with visible light. Thus, we were able to demonstrate the robustness and versatility of mpg-CN as a photoredox catalyst beyond water splitting and the activation of oxygen. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
相关化合物
相关文献:
C.W. Lindsley et al.
[Tetrahedron Lett. 43 , 4225, (2002)]