Chemical Communications
2007-03-14
Actinide-mediated coupling of 4-fluorobenzonitrile: synthesis of an eight-membered thorium(IV) tetraazametallacycle.
Eric J Schelter, David E Morris, Brian L Scott, Jaqueline L Kiplinger
文献索引：Chem. Commun. (Camb.) (10) , 1029-31, (2007)
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摘要
An eight-membered thorium(IV) tetraazamacrocycle is produced by the sequential, metal-mediated coupling of four equivalents of 4-fluorobenzonitrile; its formation is consistent with the involvement of an imido intermediate, generated from a thorium ketimide complex.
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