Organic Letters 2012-04-06

Cationic Pd(II)-catalyzed highly enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes with arylboronic acids.

Kun Shen, Xiuling Han, Xiyan Lu

文献索引：Org. Lett. 7th ed., 14 , 1756-1759, (2012)

全文：HTML全文

摘要

Cationic Pd(II)-catalyzed enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes was developed without the necessity of a redox system.

相关化合物

  • [Pd(dppp)(H2O)2](...
  • 4-溴苯硼酸
  • 4-氯苯硼酸

相关文献：

Cationic palladium complex catalyzed diastereo- and enantioselective tandem annulation of 2-formylarylboronic acids with allenoates.

2009-10-01

[Org. Lett. 11 , 4366-4369, (2009)]

Control of chemoselectivity by counteranions of cationic palladium complexes: a convenient enantioselective synthesis of dihydrocoumarins.

2010-01-01

[Org. Lett. 12 , 108, (2010)]

Cationic palladium-catalyzed [5 + 2] annulation of 2-acylmethoxyarylboronic acids and allenoates: synthesis of 1-benzoxepine derivatives.

2011-08-05

[J. Org. Chem. 76 , 6350, (2011)]

Cationic Palladium Complex-Catalyzed Diastereoselective Tandem Annulation of 2-Iminoarylboronic Acids with Substituted Alkynes: Enantioselective Synthesis of Aminoindene Derivatives by Double Asymmetric Induction Yu, X.; Lu, X.

[Adv. Synth. Catal. 353 , 2805-2813, (2011)]

更多文献...