Journal of Organic Chemistry 2013-09-06

Halonium ion mediated synthesis of 2-halomethylene-3-oxoketoxime derivatives from isoxazoline N-oxides.

Mustafa J Raihan, R R Rajawinslin, Veerababurao Kavala, Chun-Wei Kuo, Ting-Shen Kuo, Chiu-Hui He, Hsiu-Ni Huang, Ching-Fa Yao

文献索引：J. Org. Chem. 78(17) , 8872-9, (2013)

全文：HTML全文

摘要

A protocol for the N-bromosuccinimide (NBS)- and trichloroisocyanuric acid (TCCA)-mediated synthesis of novel 2-halomethylene-3-oxoketoximes via one-pot halogenation/oxidation of isoxazoline N-oxide derivatives is described here. The keto functionality of 3-ketoximes was selectively reduced by lithiumaluminum hydride to synthesize an unprecedented type of Baylis-Hillman oxime, which underwent N-O coupling to produce new isoxazoline N-oxide derivative.

相关化合物

  • 三氯异氰脲酸

相关文献：

P2X7R activation drives distinct IL-1 responses in dendritic cells compared to macrophages.

2015-08-01

[Cytokine 74 , 293-304, (2015)]

Stability and toxicity of selected chlorinated benzophenone-type UV filters in waters.

2013-01-01

[Acta Chim. Slov. 60(4) , 826-32, (2013)]

Impregnated silica nanoparticles for the reactive removal of sulphur mustard from solutions.

2009-01-30

[J. Hazard. Mater. 161 , 933-940, (2009)]

A review of toxicology studies on cyanurate and its chlorinated derivatives.

1986-11-01

[Environ. Health Perspect. 69 , 287-92, (1986)]

Effect of silver oxide/trichloroisocyanuric acid antimicrobial urinary drainage system on catheter-associated bacteriuria.

1988-01-01

[J. Urol. 139(1) , 69-73, (1988)]

更多文献...