Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide.

Tetsuaki Fujihara, Tomoya Hosoki, Yuko Katafuchi, Tomohiro Iwai, Jun Terao, Yasushi Tsuji

文献索引：Chem. Commun. (Camb.) 48 , 8012, (2012)

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摘要

Aryl formates are efficient carbon monoxide sources in palladium-catalyzed esterification of aryl halides. The carbonylation readily proceeds at ambient pressure without the use of external carbon monoxide to afford the corresponding esters in high yields.