Analytical Sciences 2012-01-01

Cold-spray ionization mass spectrometric detection of a coordination oligomer.

Kazuaki Ohara, Kentaro Yamaguchi

文献索引：Anal. Sci. 28(7) , 635-7, (2012)

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摘要

Coordination polymer (CP) formation is an unexplored area in weak-interaction chemistry due to the difficulty of monitoring the coordination process. By using cold-spray ionization mass spectrometry (CSI-MS), several kinds of coordination compounds were detected when CuI metal and the 4,7-phenanthroline organic bridged ligand were mixed in solution. The observed ion peaks could be reasonably and simply assigned to various combinations of the metal and the ligand without any fragmentation.

相关化合物

  • 碘化亚铜
  • 4,7-菲咯啉

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