Alkylation of active methylene compounds with alcohols catalyzed by an iridium complex.
Masao Morita, Yasushi Obora, Yasutaka Ishii
文献索引：Chem. Commun. (Camb.) , 2850, (2007)
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摘要
Base-free catalytic alpha-alkylation of active methylene compounds with primary alcohols was successfully achieved using an [IrCl(cod)](2) complex in the presence of PPh(3) to afford the corresponding saturated alpha-alkylated products in good yields.
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