Xanthone natural products via N-heterocyclic carbene catalysis: total synthesis of atroviridin.
Yumiko Suzuki, Yoshinori Fukuta, Shinya Ota, Masayo Kamiya, Masayuki Sato
文献索引：J. Org. Chem. 76(10) , 3960-7, (2011)
全文：HTML全文
摘要
The total synthesis of atroviridin has been accomplished by a linear route involving the N-heterocyclic carbene (NHC)-catalyzed aroylation of the fluorobenzene derivative, Claisen cyclization of the O-propargylated benzophenones, and intramolecular 1,4-addition of the quinone intermediates. The result provides a viable route to xanthone natural products.
相关化合物
相关文献：
Steric effects on atropisomerism in tetraarylporphyrins. Crossley MJ, et al.
[J. Am. Chem. Soc. 109(2) , 341-348, (1987)]
A new synthesis of benzo [b] thiophenes utilizing an interrupted Pummerer reaction. Kobayashi K, et al.
[Tetrahedron 65(12) , 2430-2435, (2009)]
Synthesis of new 1, 2, 4-triazole derivatives and their anticorrosion properties on mild steel in hydrochloric acid medium. Gurudatt DM, et al.
[J. Mol. Liq. 211 , 275-287, (2015)]