Molecular mechanism of uncaging CO2 from nitrophenylacetate provides general guidelines for improved ortho-nitrobenzyl cages.
K M Henkels, G P Boivin, E S Dudley, S J Berberich, J Gomez-Cambronero
文献索引:ChemPhysChem 12(11) , 2077-80, (2011)
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摘要
Femtosecond spectroscopy and quantum chemical calculations provide detailed insights into the specificities of the uncaging mechanism of CO2 from ortho-, meta-, and para-nitrophenylacetate. The emerging general principles allow a rational design of improved ortho-nitrophenyl cages for chemical and biological applications.Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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