Direct synthesis of alkylsilanes by platinum-catalyzed coupling of hydrosilanes and iodoalkanes.
Hikaru Inubushi, Hitoshi Kondo, Aldes Lesbani, Mariko Miyachi, Yoshinori Yamanoi, Hiroshi Nishihara
文献索引:Chem. Commun. (Camb.) 49(2) , 134-6, (2013)
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摘要
Alkyl iodides and tertiary silanes were successfully coupled with good functional group tolerance using a Pt(P(tBu)(3))(2)/(iPr)(2)EtN/CH(3)CN system. The utility of the methodology is demonstrated by the synthesis of silafluofen, a Si-containing insecticide.
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