Angewandte Chemie. International edition in English 2013-10-18

Arylation of diazoesters by a transient N-H insertion organocascade.

Tyler J Auvil, Sonia S So, Anita E Mattson

文献索引：Angew. Chem. Int. Ed. Engl. 52(43) , 11317-20, (2013)

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摘要

It takes two: A unique organocatalyzed cascade for the unsymmetric double arylation of α-nitrodiazoesters is described. This organocascade features the strategic use of carbene-activating anilines in conjunction with a urea catalyst, thus allowing for the synthesis of pharmaceutically attractive α-diarylesters through a transient NH insertion process. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

相关化合物

  • Mattson Boronate...

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