Journal of Chemical Technology and Biotechnology 1998-05-01

Differential photohydrodehalogenation reactivity of bromobenzenes (1,2,4-tribromobenzene, 1,2,3,5-tetrabromobenzene) and pentachlorobenzene: sunlight-based remediation.

P K Freeman, C M Haugen

文献索引：J. Chem. Technol. Biotechnol. 72(1) , 45-9, (1998)

全文：HTML全文

摘要

The photochemical dehalogenation of 1,2,4-tribromobenzene, 1,2,3,5-tetrabromobenzene and pentachlorobenzene in open-air solutions of acetonitrile using natural and artificial sunlight as the irradiation source has been investigated. The regiochemistry of mono-dehalogenation has been determined for 1,2,4-tribromobenzene and 1,2,3,5-tetrabromobenzene. Pentachlorobenzene did not react. 1,2,4-Tribromobenzene yielded three products, 1,4-dibromobenzene, 1,3-dibromobenzene and 1,2-dibromobenzene with isomer percentages of 52 +/- 1%, 39 +/- 2% and 9 +/- 1%, respectively. 1,2,3,5-Tetrabromobenzene yielded 1,3,5-tribromobenzene, 1,2,4-tribromobenzene and 1,2,3-tribromobenzene with relative product percentages of 60 +/- 2%, 29 +/- 2%, 11 +/- 1%.

相关化合物

  • 1,2,4-三溴苯

相关文献：

Hepatotoxicity of brominated benzenes: relationship between chemical structure and hepatotoxic effects in acute intoxication of mice.

1998-01-01

[Arch. Toxicol. 72(2) , 97-103, (1998)]

Effects of halobenzenes on growth rate of fish (Gambusia affinis).

1998-02-01

[Ecotoxicol. Environ. Saf. 39(2) , 120-30, (1998)]

Synthesis and characterization of cross-linked conjugated polymer milli-, micro-, and nanoparticles.

2004-03-26

[Angew. Chem. Int. Ed. Engl. 43(14) , 1808-11, (2004)]

Various pharmacokinetic parameters in relation to enzyme-inducing abilities of 1,2,4-trichlorobenzene and 1,2,4-tribromobenzene.

1980-07-01

[J. Toxicol. Environ. Health A 6(4) , 737-49, (1980)]

Subchronic hepatotoxicity evaluation of 1,2,4-tribromobenzene in Sprague-Dawley rats.

2012-06-01

[Int. J. Toxicol. 31(3) , 250-6, (2012)]

更多文献...