New monoacylhydrazidate-coordinated Mn2+ and Pb2+ compounds.

Juan Jin, Fu-Quan Bai, Ming-Jun Jia, Jie-Hui Yu, Ji-Qing Xu

文献索引：Dalton Trans. 41(20) , 6137-47, (2012)

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摘要

By the simple hydrothermal self-assembly, four new monoacylhydrazidate-coordinated compounds [Mn(APTH)(2)(H(2)O)] 1, [Pb(APTH)(2)]·0.25H(2)O 2, [Pb(2)(EPDH)(4)(H(2)O)] 3 and [Pb(MPDH)(2)] 4 (APTH = 3-aminophthalhydrazidate, EPDH = 5-ethylpyridine-2,3-dicarboxylhydrazidate, MPDH = 6-methylpyrinde-2,3-dicarboxylhydrazidate) were obtained. It is noteworthy that APTH was derived from the in situ reduction reaction of NPTH (3-nitrophthalhydrazide) with N(2)H(4)·H(2)O as the reducer, whereas EPDH and MPDH were derived respectively from the in situ acylation reactions of epdca and mpdca (epdca = 5-ethylpyridine-2,3-dicarboxylic acid, mpdca = 6-methylpyridine-2,3-dicarboxylic acid) with N(2)H(4)·H(2)O. The photoluminescence analysis indicates that compounds 3 and 4 possess luminescence properties with maximum emissions at 531 nm for 3, and 600 nm for 4, respectively. The density functional theory (DFT) calculations indicate that the emission for compound 3 can be ascribed to a combination of the intra-ligand and inter-ligand charge transfers, while the emission for compound 4 is assigned to the intra-ligand charge transfer.