Synthesis of oxacalixarenes incorporating nitrogen heterocycles: evidence for thermodynamic control.
Jeffrey L Katz, Bram J Geller, Rebecca R Conry
文献索引:Org. Lett. 8 , 2755, (2006)
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摘要
[structure: see text] Oxacalix[2]arene[2]hetarenes are formed in a single step by cyclooligomerization of meta-diphenols with meta-dichlorinated azaheterocycles. The high selectivity for cyclic tetramer formation results from thermodynamic product control. Macrocycles as large as oxacalix[5]arene[5]hetarenes have been isolated under nonequilibrating conditions.
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