Molecular Diversity 2006-05-01

Three-component synthesis of dialkyl 2-(alkylimino-methylene)3- (2,2,5-trimethyl-4,6-dioxo-1,3-dioxan-5-yl)-succinates.

Issa Yavari, Hasan Zare, Bita Mohtat

文献索引:Mol. Divers. 10(2) , 247-50, (2006)

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摘要

The adduct produced in the reaction between alkyl isocyanides and dialkyl acetylenedicarboxylates was trapped by 2,2,5-trimethyl-1,3-dioxane-4,6-dione (methyl Meldrum's acid), to afford highly functionalized ketenimines in good yields.


相关化合物

  • 甲基丙二酸亚异丙酯
  • 2-丁炔二酸单钾盐
  • 丁炔二酸

相关文献:

An ESR, ENDOR, and ELDOR study of tunneling rotation of a hindered methyl group in x-irradiated 2, 2, 5-trimethyl-1, 3-dioxane-4, 6-dione crystals. Geoffroy M, et al.

[J. Chem. Phys. 70(9) , 4238-42, (2008)]

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