Molecular Diversity
2006-05-01
Three-component synthesis of dialkyl 2-(alkylimino-methylene)3- (2,2,5-trimethyl-4,6-dioxo-1,3-dioxan-5-yl)-succinates.
Issa Yavari, Hasan Zare, Bita Mohtat
文献索引:Mol. Divers. 10(2) , 247-50, (2006)
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摘要
The adduct produced in the reaction between alkyl isocyanides and dialkyl acetylenedicarboxylates was trapped by 2,2,5-trimethyl-1,3-dioxane-4,6-dione (methyl Meldrum's acid), to afford highly functionalized ketenimines in good yields.
相关化合物
相关文献:
An ESR, ENDOR, and ELDOR study of tunneling rotation of a hindered methyl group in x-irradiated 2, 2, 5-trimethyl-1, 3-dioxane-4, 6-dione crystals. Geoffroy M, et al.
[J. Chem. Phys. 70(9) , 4238-42, (2008)]