Chemistry: A European Journal 2010-06-18

Rapid and selective catalytic oxidation of secondary alcohols at room temperature by using (N-heterocyclic carbene)-ni(0) systems.

Christophe Berini, Ole H Winkelmann, Jennifer Otten, David A Vicic, Oscar Navarro

文献索引：Chemistry 16(23) , 6857-60, (2010)

全文：HTML全文

摘要

The selective, anaerobic catalytic oxidation of secondary alcohols at room temperature by using an in situ (N-heterocyclic carbene)-Ni(0) system is presented. The use of non-anhydrous, non-degassed 2,4-dichlorotoluene as both the oxidant and the solvent allows for very short reaction times and very high yields. In addition, a well-defined (N-heterocyclic carbene)-Ni(0) complex was synthesized and applied to these oxidation reactions.

相关化合物

  • 2,4-二氯甲苯

相关文献：

Metabolism of dichloromethylcatechols as central intermediates in the degradation of dichlorotoluenes by Ralstonia sp. strain PS12.

2002-10-01

[J. Bacteriol. 184(19) , 5261-74, (2002)]

Development of a solid-phase microextraction-gas chromatography-tandem mass spectrometry method for the analysis of chlorinated toluenes in environmental waters.

2009-04-03

[J. Chromatogr. A. 1216(14) , 2816-24, (2009)]

[Gas chromatographic determination of 2,4-dichlorotoluene in water].

1988-03-01

[Gig. Sanit. (3) , 44-5, (1988)]

[Hygienic standards for 2,4-dichlorotoluene in reservoir water].

1988-02-01

[Gig. Sanit. (2) , 80-1, (1988)]

Measurement and theory of hydrogen bonding contribution to isosteric DNA base pairs.

2012-02-15

[J. Am. Chem. Soc. 134(6) , 3154-63, (2012)]

更多文献...