Inorganic Chemistry 2004-02-23

Synthesis and structural characterization of a terminal hydroxide containing alumoxane via hydrolysis of aluminum hydrides.

Ying Peng, Guangcai Bai, Hongjun Fan, Denis Vidovic, Herbert W Roesky, Jörg Magull

文献索引：Inorg. Chem. 43(4) , 1217-9, (2004)

全文：HTML全文

摘要

A novel terminal hydroxide containing dinuclear alumoxane LAl(OH)OAlL(OCH=N-tBu) (3; L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) was prepared by treatment of aluminum dihydride LAlH2 (1) and tert-butyl isocyanate in the presence of trace amounts of water and alternatively from 1 and LAlH(OCH=N-tBu) (2) with water. Compound 2 was obtained from the reaction of 1 and tert-butyl isocyanate.

相关化合物

  • 叔丁基异氰酸酯

相关文献：

Molybdenum oxo-imido aryloxide complexes: oxo analogues of olefin metathesis catalysts.

2006-05-29

[Inorg. Chem. 45(11) , 4556-61, (2006)]

Versatile stereoselective cycloadditions between heterocumulenes and phosphagermaallene Tip(tBu)Ge=C=PMes*: experimental and theoretical investigations.

2011-11-04

[Chemistry 17(45) , 12763-72, (2011)]

Inhibition of carcinogen-induced neoplasia by sodium cyanate, tert-butyl isocyanate, and benzyl isothiocyanate administered subsequent to carcinogen exposure.

1981-08-01

[Cancer Res. 41(8) , 2991-4, (1981)]

更多文献...