Determination of amino acid enantiopurity and absolute configuration: synergism between configurationally labile metal-based receptors and dynamic covalent interactions.
Francesca A Scaramuzzo, Giulia Licini, Cristiano Zonta
文献索引:Chemistry 19(49) , 16809-13, (2013)
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摘要
Reliable determination of the enantiomeric excess of free amino acids can be obtained by measuring the induced circular dichroism of a multicomponent assembly formed by a modified tris(2-pyridylmethyl)amine ligand, a zinc salt, and the amino acid of interest. The systems furnish reliable information for all natural amino acids. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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