A ceramic electrochemical microreactor for the methoxylation of methyl-2-furoate with direct mass spectrometry coupling.
Virginie Mengeaud, Olivier Bagel, Rosaria Ferrigno, Hubert H Girault, Akhtar Haider
文献索引：Lab Chip 2(1) , 39-44, (2002)
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摘要
A ceramic electrochemical reactor (CEM) devoted to electrosyntheses was developed. The CEM was constituted by the assembly of five structured ceramic layers. On one layer, platinum interdigitated band electrodes with a submillimetre interelectrode gap were screen-printed. The microreactor chamber was constituted by seven channels and its volume was less than 100 microL. After a sintering step at 850 degree C for 1 h, the CEM appeared as a solid and compact unit. The CEM was directly connected to the six port valve of a mass spectrometer allowing an on-line sampling and analysis of the reaction mixture. The methoxylation of the methyl-2-furoate was carried out and the effect of the residence time in the CEM was investigated thanks to mass spectrometry analyses.