Electroreduction of N-methylphthalimide in room temperature ionic liquids under insonated and silent conditions.
Constanza Villagrán, Craig E Banks, William R Pitner, Christopher Hardacre, Richard G Compton
文献索引:Ultrason. Sonochem. 12(6) , 423-8, (2005)
全文:HTML全文
摘要
The selective electroreduction N-methylphthalimide to 3-hydroxy-2-methyl-isoindolin-1-one has been performed in ionic liquids using phenol as a proton donor under silent and ultrasonic conditions. A significant increase in the rate of electroreduction is shown using ultrasonic activation and in addition high current efficiencies were observed. Some decomposition of the ionic liquid was found to have occurred under exposure to ultrasound.
相关化合物
相关文献:
Photoreduction of N-methylphthalimide with 2, 3-dimethyl-2-butene. Evidence for reaction through an electron transfer generated ion pair. Mazzocchi PH and Klingler L.
[J. Am. Chem. Soc. 106(24) , 7567-72, (1984)]
Single electron transfer induced photoaddition reactions of silyl enol ether to N-methylphthalimide. Oh SW, et al.
[Bull. Korean Chem. Soc. 28(4) , 629, (2007)]
Nitration of N-alkylphthalimides. Williams FJ and Donahue PE.
[J. Org. Chem. 43(8) , 1608-10, (1978)]